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610304-81-9

610304-81-9 Structure

610304-81-9 Structure
IdentificationBack Directory
[Name]

(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN
[CAS]

610304-81-9
[Synonyms]

(S)-BINAPINE
(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN
(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN
(3S,3'S,4S,4'S,11bS,11'bS)-(+)-4,4'-Di-t-butyl-4,4',5,5'-tetrahydro-3,3'-bi-3H-dinaphtho[2,1-c:1',2'-e]phosphepin (S)-BINAPINE
(3S,3'S,4S,4'S,11bS,11'bS)-(+)-4,4'-Di-t-butyl-4,4',5,5'-tetrahydro-3,3'-bi-3H-dinaphtho[2,1-c:1',2'-e]phosphepin,97%(S)-BINAPINE
[Molecular Formula]

C52H48P2
[MDL Number]

MFCD06658119
[MOL File]

610304-81-9.mol
[Molecular Weight]

734.89
Chemical PropertiesBack Directory
[Melting point ]

>300 °C (dec.)(lit.)
[form ]

Powder
[color ]

white to light yellow
[Sensitive ]

air sensitive
[CAS DataBase Reference]

610304-81-9
Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reaction]

  1. Rhodium complex used in asymmetric hydroformylation reactions.
  2. Ligand-palladium complex used in enantioselective carbonyl-ene reactions.
  3. Nickel-catalyzed asymmetric transfer hydrogenation of olefins for the synthesis of αand βamino acids.
  4. Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines.
  5. Nickel/ligand catalyst used in the enantioselective reductive amination of ketones with both arylamines and benzhydrazide,
  6. Rh-Binapine and Pd-Binapine complexes form excellent catalysts for asymmetric (transfer) hydrogenation of aryl substituted olefins to form β-amino acids.
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