| Identification | Back Directory | [Name]
(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN | [CAS]
610304-81-9 | [Synonyms]
(S)-BINAPINE
(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN
(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN
(3S,3'S,4S,4'S,11bS,11'bS)-(+)-4,4'-Di-t-butyl-4,4',5,5'-tetrahydro-3,3'-bi-3H-dinaphtho[2,1-c:1',2'-e]phosphepin (S)-BINAPINE
(3S,3'S,4S,4'S,11bS,11'bS)-(+)-4,4'-Di-t-butyl-4,4',5,5'-tetrahydro-3,3'-bi-3H-dinaphtho[2,1-c:1',2'-e]phosphepin,97%(S)-BINAPINE | [Molecular Formula]
C52H48P2 | [MDL Number]
MFCD06658119 | [MOL File]
610304-81-9.mol | [Molecular Weight]
734.89 |
| Questions And Answer | Back Directory | [Reaction]
- Rhodium complex used in asymmetric hydroformylation reactions.
- Ligand-palladium complex used in enantioselective carbonyl-ene reactions.
- Nickel-catalyzed asymmetric transfer hydrogenation of olefins for the synthesis of αand βamino acids.
- Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines.
- Nickel/ligand catalyst used in the enantioselective reductive amination of ketones with both arylamines and benzhydrazide,
- Rh-Binapine and Pd-Binapine complexes form excellent catalysts for asymmetric (transfer) hydrogenation of aryl substituted olefins to form β-amino acids.
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