63348-81-2

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63348-81-2 Structure

Identification	Back Directory
[Name] BORON MONOCHLORIDE-METHYL SULFIDE COMPLEX
[CAS] 63348-81-2
[Synonyms] Chloroborane methyl MONOCHLOROBORANE-METHYLSULFIDE Monochloroborane-dimethyl sulfide CHLOROBORANE-METHYL SULFIDE COMPLEX Chloro(dimethyl sulfide)dihydroboron Chloroborane-methyl sulfide 1:1 complex Monochloroborane-dimethyl sulfide (1:1) MONOCHLOROBORANE-METHYL SULFIDE COMPLEX Monochloroborane-dimethylsulfide complex BORON MONOCHLORIDE-METHYL SULFIDE COMPLEX Boron, chlorodihydrothiobismethane-, (T-4)- Boron monochloride methyl sulfide complex, monoChloroborane methyl sulfide complex Chloroborane methyl sulfide complex,Boron monochloride methyl sulfide complex, monoChloroborane methyl sulfide complex
[Molecular Formula] C2H9BClS
[MDL Number] MFCD00013210
[MOL File] 63348-81-2.mol
[Molecular Weight] 111.41

Chemical Properties	Back Directory
[density ] 1.059 g/mL at 25 °C (lit.)
[Fp ] 76 °F
[solubility ] soluble in Benzene, Chloroform
[form ] Oil
[color ] Clear Colourless
[Stability:] Hygroscopic, Moisture Sensitive

Hazard Information	Back Directory
[Uses] Reactant for: Substitution reactions Boronation reactions Preparation of diborylamines Preparation of unsymmetrical borafluorenes via low-temperature carbon-hydrogen activation reactions Asymmetrical aldol reactions with a-chiral aldehydes Addition reaction with α-pinene
[Preparation] Monochloroborane-dimethyl sulfide is prepared by redistribution of Borane-Dimethyl Sulfide (BMS) and Boron Trichloride. SMe2 and by the reaction of BMS with CCl4. The reagent is in equilibrium with approximately 15% each of BHCl2.SMe2 and BMS.
[reaction suitability] reagent type: reductant
[Precautions] corrosive liquid; flammable; stench; reacts violently with water. Handle and store under nitrogen or argon. Stable indefinitely when stored under nitrogen at 25 °C. Use in a fume hood.

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