| Identification | Back Directory | [Name]
TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE | [CAS]
64443-05-6 | [Synonyms]
tetrakis(acetonitrile)copper(I)
tetrakis(acetonitrile)copper hexa-fluorophosph
tetrakis(acetonitrile)copper(I) hexa-fluorophosph
Tetrakis(acetonitrle)copper(I) Hexafluorophosphate
Cuprous tetrakis(acetonitrile) hexafluorophosphate
Tetrakis(acetonitrile)copper [] hexafluorophosphate
Tetrakis(acetonitrile)copper [Ⅰ] hexafluorophosphate
Copper(I) tetrakis(acetonitrile) hexafluorophosphate
TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE
Tetrakis(acetonitrile)copper(I)hexafluorophosphate,98+%
Tetrakis(acetonitrile)copper(I) hexafluorophosphate 97%
Copper(1+), tetrakis(acetonitrile)-, (T-4)-, hexafluorophosphate(1-) | [Molecular Formula]
C8H12CuF6N4P | [MDL Number]
MFCD00064810 | [MOL File]
64443-05-6.mol | [Molecular Weight]
372.72 |
| Chemical Properties | Back Directory | [Melting point ]
160 °C (dec.)(lit.)
| [storage temp. ]
Inert atmosphere,Store in freezer, under -20°C | [form ]
solid | [color ]
white to light blue | [Sensitive ]
air sensitive, moisture sensitive | [InChI]
InChI=1S/4C2H3N.Cu.F6P/c4*1-2-3;;1-7(2,3,4,5)6/h4*1H3;;/q;;;;+1;-1 | [InChIKey]
GNQXUMGHBSAQBV-UHFFFAOYSA-N | [SMILES]
[P-](F)(F)(F)(F)(F)F.C(#N)C.C(#N)C.C(#N)C.C(#N)C.[Cu+] |
| Questions And Answer | Back Directory | [Reaction]
- Useful catalyst for the Ullmann synthesis.
- Catalytic asymmetric [2,3]-Sigmatropic rearrangement of sulfur ylides.
- Precatalyst for enantioselective N–H insertion reactions with diazoesters and anilines.
|
| Hazard Information | Back Directory | [Uses]
Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively.
It can also be used as a copper precursor:
- For the formation of Cu2S/CdS nanorod junctions by cationic exchange process.
- To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].
- To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.
- For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.
| [reaction suitability]
core: copper
reagent type: catalyst | [Synthesis]
Tetrakis(acetonitrile)copper (I) hexafluorophosphate can be obtained by reacting Cu2O with hexafluorophosphoric acid. |
|
| Company Name: |
LaaJoo Gold
|
| Telephone: |
021-60702684 18516024827 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList20079/0_EN.htm |
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|