| Identification | Back Directory | [Name]
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE | [CAS]
65012-74-0 | [Synonyms]
(bicyclo(2.2.1)hepta-2,5-diene)((2S,3S)-bis(diphe
bicycloheptadiene(diphenylphosphino)butane rhodium ClO4
(BICYCLO(2.2.1)HEPTA-2,5-DIENE)((2S,3S)- BIS(DIPHENYLPHOSPHINO)BUTANE)RH(I)CL04
(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-BIS(diphenylphosphino)-butane] rhodium(I)
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE | [Molecular Formula]
C35H36ClO4P2Rh | [MDL Number]
MFCD00078983 | [MOL File]
65012-74-0.mol | [Molecular Weight]
720.96 |
| Hazard Information | Back Directory | [Uses]
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE is a catalyst precursor used in the asymmetric hydrogenation of amino acid precursors, as well as in transfer hydrogenation and hydrosilation reactions
| [Synthesis]
Cationic rhodium-chiraphos complexes are usually prepared in situ or from the procedure given below. In reactions employing the various rhodium-chiraphos complexes, the diene ligand is frequently hydrogenated prior to catalysis to afford the active solvated catalyst precursors [RhS2(chiraphos)]+.
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