ChemicalBook--->CAS DataBase List--->6627-89-0

6627-89-0

6627-89-0 Structure

6627-89-0 Structure
IdentificationBack Directory
[Name]

tert-Butyl phenyl carbonate
[CAS]

6627-89-0
[Synonyms]

Einecs 229-601-8
BUTTPARK 52\11-34
t-Butyl phenyl carbonate
ert-Butyl phenyl carbonate
tart-Butylphenyl carbonate
TERT-BUTYL PHENYL CARBONATE
(2-tert-butylphenyl) carbonate
(tert-Butoxycarbonyloxy)benzene
tert-Butyl phenyl carbonate 98%
tert-Butyl Phenyl Carbonate >
Carbonic acid tert-butylphenyl ester
2-Methyl-2-propanyl phenyl carbonate
Carbonicacidtert-butylesterphenylester
tert-Butyl phenyl carbonate≥ 98%(HPLC)
Carbonic acid O-phenyl O-tert-butyl ester
Carbonic acid O-tert-butyl O-phenyl ester
Carbonic acid, 1,1-dimethylethyl phenyl ester
tert-Butyl phenyl carbonate Carbonic acid tert-butyl phenyl ester
[EINECS(EC#)]

229-601-8
[Molecular Formula]

C11H14O3
[MDL Number]

MFCD00008804
[MOL File]

6627-89-0.mol
[Molecular Weight]

194.23
Chemical PropertiesBack Directory
[Boiling point ]

83 °C0.6 mm Hg(lit.)
[density ]

1.05 g/mL at 20 °C(lit.)
[refractive index ]

n20/D 1.480
[Fp ]

214 °F
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

Chloroform (Slightly)
[form ]

Liquid or Low Melting Solid
[color ]

Colorless
[Water Solubility ]

Slightly soluble in water.
[BRN ]

2361602
[NIST Chemistry Reference]

Carbonic acid 1,1-dimethylethyl ester(6627-89-0)
Safety DataBack Directory
[Safety Statements ]

23-24/25
[WGK Germany ]

3
[F ]

21
[HS Code ]

29209090
Hazard InformationBack Directory
[Chemical Properties]

Clear light yellow liquid
[Uses]

tert-Butyl phenyl carbonate is used in determination of octanol-water partition coefficients by microemulsion electrokinetic chromatography. It is also used in the synthesis of 2-nitroindoles and as a reagent for mono-Boc protection of α,ω-diamines.
[Purification Methods]

If IR is free from OH, then purify it by redistillation; otherwise dissolve it in Et2O, wash it with 5% HCl, then H2O, dry it (MgSO4), evaporate and distil it through a Claisen head under vacuum. Care should be taken as distillation of large quantities can lead to decomposition with liberation of CO2 and isobutylene; use the necessary precautions. [Carpino J Am Chem Soc 79 98 1957, Beilstein 6 IV 629.]
Spectrum DetailBack Directory
[Spectrum Detail]

tert-Butyl phenyl carbonate(6627-89-0)MS
tert-Butyl phenyl carbonate(6627-89-0)1HNMR
tert-Butyl phenyl carbonate(6627-89-0)13CNMR
tert-Butyl phenyl carbonate(6627-89-0)IR1
tert-Butyl phenyl carbonate(6627-89-0)Raman
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