| Identification | Back Directory | [Name]
FENOXAPROP-P-ETHYL | [CAS]
66441-23-4 | [Synonyms]
puma
whip
BBC3
Exel
Supet
JFY-1
WRNIP1
option
hoe33171
FLJ22526
(R)-PUMA
Anti-JFY1
Anti-PUMA
hoe-a25-01
FENOVA(TM)
WHIP SUPER
Horizon[R]
RP11-420G6.2
fenoxaprop-et
Acclaim[R] 1EC
Fenoxaprop-ethy
fenoxapoptethyl
FENOXAPROP-ETHYL
FENOXAPROP-P-ETHYLl
Pume Super (Hoechst)
(R)-FENOXAPROP-P-ETHYL
putative helicase RUVBL
Bcl-2-binding component 3
Fenoxaprop-ethyl Standard
FENOXAPROP ETHYL, 100MG, NEAT
Fenoxaprop-ethyl @100 μg/mL in MeOH
Werner helicase interacting protein
Anti-BBC3 antibody produced in goat
Fenoxaprop ethyl 100mg [66441-23-4]
Werner helicase interacting protein 1
p53 up-regulated modulator of apoptosis
FENOXAPROP-ETHYL RACEMATE, PESTANAL,250
Fenoxaprop-ethyl@1000 μg/mL in Acetonitrile
fenoxaprop-ethyl(stereochemistryunspecified)
ANTI-PUMA BH3 DOMAIN antibody produced in rabbit
Fenoxaprop-ethyl Solution in Methanol, 1000μg/mL
Anti-WRNIP1 (C-terminal) antibody produced in goat
Ethyl-2-[4-(6-chloro-2-benzoxazolyloxy)phenoxy]propionate
2-[4-[(6-chloro-2-benzoxazolyl)oxy]phenoxy]-, ethyl ester
Ethyl-2-[4-[(6-chlorbenozoxazol-2-yl)oxy]phenoxy]propionat
ethyl 2-[4-[(6-chlorobenzoxazol-2-yl)oxy]phenoxy]propionate
ethyl(d+)-2-(4-(6-chlor-2-benzoxazolyloxy)phenoxy)propanoate
(+,)-2-ethyl-(4-(6-chloro-2-benzoxazolyloxy)phenoxy)propanoate
Ethyl 2-{4-[(6-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy}propanoate
(+/-)-2-(4-((6-chloro-2-benzoxazolyl)oxy)phenoxy)propanoicacidethylester
2-[4-[(6-chloro-2-benzoxazolyl)oxy]phenoxy]-,ethylester,(±)-Propanoicacid
propanoicacid,2-(4-((6-chloro-2-benzoxazolyl)oxy)phenoxy)-,ethylester,(+-)
Propanoicacid,2-[4-[(6-chloro-2-benzoxazolyl)oxy]phenoxy]-,ethylester,(±)-
ethyl 2-[4-[(6-chlorobenzoxazol-2-yl)oxy]phenoxy]propionate fenoxaprop-ethyl
(±)-Propanoic acid Ethyl-2-[4-(6-chloro-2-benzoxazolyloxy) phenoxy] propionate | [EINECS(EC#)]
266-362-9 | [Molecular Formula]
C18H16ClNO5 | [MDL Number]
MFCD01310637 | [MOL File]
66441-23-4.mol | [Molecular Weight]
361.78 |
| Chemical Properties | Back Directory | [Appearance]
Colorless or white solid. Liquid form is dark
brown with an aromatic hydrocarbon odor. | [Melting point ]
84-85° | [alpha ]
-1～+1°(20℃/D)(c=1, 1,4-dioxane) | [Boiling point ]
bp 200° at 100 Pa | [density ]
1.2523 (rough estimate) | [refractive index ]
1.6500 (estimate) | [storage temp. ]
-20°C | [form ]
neat | [pka]
-0.08±0.30(Predicted) | [biological source]
goat | [Henry's Law Constant]
6.2×102 mol/(m3Pa) at 25℃, Ebert et al. (2023) | [Major Application]
agriculture
environmental | [InChI]
1S/C18H16ClNO5/c1-3-22-17(21)11(2)23-13-5-7-14(8-6-13)24-18-20-15-9-4-12(19)10-16(15)25-18/h4-11H,3H2,1-2H3 | [InChIKey]
PQKBPHSEKWERTG-UHFFFAOYSA-N | [SMILES]
CCOC(=O)C(C)Oc1ccc(Oc2nc3ccc(Cl)cc3o2)cc1 | [EPA Substance Registry System]
Fenoxaprop-ethyl (66441-23-4) |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless or white solid. Liquid form is dark
brown with an aromatic hydrocarbon odor. | [General Description]
Coarse light beige to brown powder. Selective herbicide. | [Agricultural Uses]
Herbicide: Used to control annual and perennial grassy weeds in potatoes, soy beans, beans, beets, vegetables, flax,
ground nuts, rape and cotton. Not approved for use in EU
countries. Not registered for use in the U.S. There are
17 global suppliers. | [Trade name]
ACCLAIM®[C]; DEPON®; EXCEL®;
FENOXYPROP®; FURORE®; HOE 033171®; HOE-A
25-01®; OPTION® Fenoxaprop-ethyl; PUMA®;
WHIP® | [Potential Exposure]
A chlorophenoxy/aryloxyphenoxypropionate herbicide used to control annual and perennial
grassy weeds in potatoes, soy beans, beans, beets, vegetables, flax, ground nuts, rape, and cotton.
Incompatibilities: Decomposed by acids and alkalis. May
react with strong oxidizers such as chlorates, peroxides,
nitrates, etc | [First aid]
UN3077 Environmentally hazardous substances,
solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required | [Shipping]
UN3077 Environmentally hazardous substances,
solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required. | [Incompatibilities]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids. Seek
medical attention immediately. If this chemical contacts the
skin, remove contaminated clothing and wash immediately
with soap and water. Seek medical attention immediately.
If this chemical has been inhaled, remove from exposure,
begin rescue breathing (using universal precautions) if
breathing has stopped, and CPR if heart action has stopped.
Transfer promptly to a medical facility. When this chemical
has been swallowed, get medical attention. Give large
quantities of water and induce vomiting. Do not make an
unconscious person vomit. Do not induce vomiting when
formulations containing petroleum solvents are ingested.
| [Description]
Fenoxaprop-ethyl is an obsolete phenoxypropionic herbicide and auxin plant growth regulator for control of woody plants and broadleaved weeds on land and in aquatic situations. It has a low aqueous solubility but is soluble in many organic solvents. It is not normally persistent in soil systems but may be in water systems depending on local conditions. It is not volatile and, based on its physic-chemical properties, it is not expected to leach to groundwater. Fenoxaprop-ethyl is moderately toxic to fish, aquatic invertebrates, algae and earthworms. Human oral toxicity is considered to be low but it may be an irritant. No information on chronic health impacts have been identified. | [Waste Disposal]
In accordance with
40CFR165, follow recommendations for the disposal of
pesticides and pesticide containers. Containers must be disposed of properly by following package label directions or
by contacting your local or federal environmental control
agency, or by contacting your regional EPA office | [Uses]
Fenoxaprop-ethyl is a pesticide. | [Uses]
Fenoxaprop-ethyl is a selective, postemergence herbicide for control of annual and perennial grass weeds in crops such as beans, beets, cotton, groundnuts, potatoes and other vegetables.
| [Definition]
ChEBI: Fenoxaprop ethyl is an aromatic ether. | [Production Methods]
The commercial production of fenoxaprop-ethy; begins with the construction of the benzoxazole ether intermediate, typically formed by reacting 6-chlorobenzoxazole with a phenoxypropionic acid derivative. This intermediate is then esterified with ethanol to produce the ethyl ester form -fenoxaprop-ethyl. Since no chiral resolution is applied during synthesis, both enantiomers are retained in the final product. | [Mechanism of action]
Selective. Acetyl CoA carboxylase inhibitor (ACCase) - distrupts fatty acid biosynthesis and lipid formation. | [Environmental Fate]
Soil. Hydrolyzes rapidly in soil forming fenoxaprop acid, ethyl alcohol, 6-chloro-2,3dihydrobenzoxazole-2-one and 4-(6-chloro-2-benzoxazolyloxy) phenol (Wink and Luley, 1988; Humburg et al., 1989). Under aerobic and anaerobic conditions, the half-life was less than 24 hours (Humburg et al., 1989).
Plant. The major degradation product identified in crabgrass, oats and wheat was 6chloro-2,3-dihydrobenzoxazol (Lefsrud and Hall, 1989).
Photolytic. Susceptible to degradation by UV light (Humburg et al., 1989).
| [Pesticide Type]
Herbicide |
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