| Identification | Back Directory | [Name]
4-Bromobenzenesulfonyl Azide | [CAS]
6647-76-3 | [Synonyms]
4-Bromobenzenesulfonyl Azide | [Molecular Formula]
C6H4BrN3O2S | [MDL Number]
MFCD11632085 | [MOL File]
6647-76-3.mol | [Molecular Weight]
262.084 |
| Hazard Information | Back Directory | [Uses]
4-Bromobenzenesulfonyl Azide is a 1,3-dipolar reagent that undergoes cycloaddition to vinyl and alkynyl ethers[1]. | [Preparation]
4-Bromobenzenesulfonyl Azide is prepared by the reaction of 4-Bromobenzenesulfonyl Chloride with excess Sodium Azide in a
water-ethanol mixture[2-3]. | [storage]
4-Bromobenzenesulfonyl Azide should be used in solution. Azides are prone to violent detonation upon
thermal, electrical, and mechanical shock. | [References]
1. 1,3-Dipolar Cycloaddition Chemistry; Lwowski, W., Ed.; Wiley: New York, 1984; Vol. 1, p 817.
2. Curtius, T. JPC 1930, 125, 303.
3. Reagan, M. T.; Nickon, A. JACS 1968, 90, 4096. |
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