| Identification | Back Directory | [Name]
Phenyl-t-butylether | [CAS]
6669-13-2 | [Synonyms]
NSC 78717
tert-Butoxybenzene
Phenyl tert-butyl ether
2-Methyl-2-phenoxypropane
(1,1-Dimethylethoxy)benzene
tert-Butyl phenyl ether, 98%
Benzene, (1,1-dimethylethoxy)-
Inchi=1/C10H14o/C1-10(2,3)11-9-7-5-4-6-8-9/H4-8H,1-3h | [Molecular Formula]
C10H14O | [MDL Number]
MFCD00049018 | [MOL File]
6669-13-2.mol | [Molecular Weight]
150.22 |
| Chemical Properties | Back Directory | [Melting point ]
-17--16℃ | [Boiling point ]
184°C | [density ]
0.924 | [refractive index ]
1.488 | [Fp ]
184°C | [storage temp. ]
Sealed in dry,Room Temperature |
| Questions And Answer | Back Directory | [Synthesis]
A 4-mL vial was charged with bromobenzene (63 mg, 0.40 mmol), Pd(dba)2 (11.5 mg, 0.0200 mmol), Ph5FcP-(t-Bu)2 (14.2 mg, 0.0200 mmol), and sodium tert-butoxide (47 mg, 0.48 mmol). Anhydrous toluene (2 mL) was added, and the vial was sealed with a cap containing a PTFE septum and removed from the dry box. The reaction mixture was stirred at room temperature for 23 h. The reaction solution was then adsorbed onto silica gel, and the product was isolated by eluting with EtOAc/hexanes (0 to 10% gradient) to give the ether (58 mg, 97%).
Reference: Kataoka, N.; Shelby, Q.; Stambuli, J. P.; Hartwig, J. F. J. Org. Chem. 2002, 67, 5553–5566.
 |
| Hazard Information | Back Directory | [Uses]
tert-Butoxybenzene was studied in the analysis of the color and flavor improvement of different starter cultures on northern air-dried sausage. |
|
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
|
| Telephone: |
0573-85285100 18627885956 |
| Website: |
https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
|