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67179-23-1

67179-23-1 Structure

67179-23-1 Structure
IdentificationBack Directory
[Name]

MAGNESIUM GERMANATE
[CAS]

67179-23-1
[Synonyms]

MAGNESIUM GERMANATE
Germanium dimagnesium oxide
Magnesium germanate(iv) (mg2geo4)
Magnesium orthogermanate (mg2geo4)
Germanium magnesium oxide (gemg2o4)
Germanium magnesium oxide (mg2geo4)
Germanate (geo44-), magnesium (1:2), (T-4)-
[Molecular Formula]

GeMgO3
[MDL Number]

MFCD00673108
[MOL File]

67179-23-1.mol
[Molecular Weight]

144.943
Hazard InformationBack Directory
[Description]

Magnesium germanate can be formed by firing the oxides together at about 900°C.
MgO + GeO2?MgGeO3
This salt has the perovskite structure. The lattice parameters are: a = 4.9375 ?, c = 13.743 ?, V = 290.15 ?3. It occurs as the mineral, “majorite”, with lattice parameters of: a = 11.051 ?, b = 11.051 ?, c = 11.480 ?, α= β = γ = 90°.
MgGeO3 is polymorphic. It forms several types of pyroxenes. Pyroxene is one of the important constituent minerals of the earth’s crust and upper mantle. , space group = I41/A. There are four (4) magnesium germanates known as shown in the following phase diagram of the system, MgO–GeO2 where each compound can be obtained by varying the MgO/GeO2 mol ratios before firing (Fig. 5.55). MgGeO3 is polymorphic. It forms several types of pyroxenes. Pyroxene is one of the important constituent minerals of the earth’s crust and upper mantle.
[Uses]

Magnesium germanate, when activated by manganese has long been used in fluorescent lamps. The emission spectrum of Mg4GeO6:0.01Mn2+ has been found to depend on the temperature of preparation.
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