| Identification | Back Directory | [Name]
2-(Dicyclohexylphosphino)-1-phenyl-1H-pyrrole | [CAS]
672937-60-9 | [Synonyms]
cataCXium(R) PCy
N-Phenylpyrrol-2-yldicyclohexylphosphine
N-Phenyl-2-(dicyclohexylphosphino)pyrrole,90%
2-(Dicyclohexylphosphino)-1-phenyl-1H-pyrrole
Dicyclohexyl(1-phenyl-1H-pyrrol-2-yl)phosphine
2-(Dicyclohexylphosphino)-1-phenyl-1H-pyrrole 95%
N-Phenyl-2-(dicyclohexylphosphino)pyrrole [cataCXiuM PCy]
N-Phenyl-2-(dicyclohexylphosphino)pyrrole, 90% [cataCXium(R) PCy] | [Molecular Formula]
C22H30NP | [MDL Number]
MFCD05861613 | [MOL File]
672937-60-9.mol | [Molecular Weight]
339.454 |
| Chemical Properties | Back Directory | [Melting point ]
92°C | [Boiling point ]
482.8±18.0 °C(Predicted) | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
Powder | [pka]
-6.24±0.70(Predicted) | [color ]
white to yellow | [Sensitive ]
air sensitive | [BRN ]
9649724 | [InChI]
1S/C22H30NP/c1-4-11-19(12-5-1)23-18-10-17-22(23)24(20-13-6-2-7-14-20)21-15-8-3-9-16-21/h1,4-5,10-12,17-18,20-21H,2-3,6-9,13-16H2 | [InChIKey]
RVFZOTGUPNHVRA-UHFFFAOYSA-N | [SMILES]
C1CCC(CC1)P(C2CCCCC2)c3cccn3-c4ccccc4 | [CAS DataBase Reference]
672937-60-9 |
| Hazard Information | Back Directory | [Chemical Properties]
White to yellow powder | [General Description]
sold in collaboration with Solvias AG | [reaction suitability]
reaction type: Asymmetric synthesis
reagent type: ligand
reaction type: Aminations
reagent type: ligand
reaction type: Heck Reaction
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling |
| Questions And Answer | Back Directory | [Reactions]
- Useful ligand for the Ru-catalyzed amination of diols.
- Direct amination of secondary alcohols with ammonia.
- Amino-alcohol cyclization to lactams or cyclic amines.
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