| Identification | Back Directory | [Name]
1-(2-METHOXYPHENYL)-2-(DICYCLOHEXYLPHOSPHINO)PYRROLE | [CAS]
672937-63-2 | [Synonyms]
CATACXIUM OMECY
cataCXium? POMeCy
cataCXium(R) POMeCy
95% [cataCXiuM POMeCy]
1-(2-METHOXYPHENYL)-2-(DICYCLOHEXYLPHOSPHINO)PYRROLE
2-(Dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole
2-(Dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole 95%
1-(2-Methoxyphenyl)-2-(dicyclohexylphosphino)pyrrole, min. 95%
1-(2-Methoxyphenyl)-2-(dicyclohexylphosphino)pyrrole,min.95%[cataCXiumPOMeCy]
1-(2-Methoxyphenyl)-2-(dicyclohexylphosphino)pyrrole, min. 95% [cataCXium(R) POMeCy] | [Molecular Formula]
C23H32NOP | [MDL Number]
MFCD06658122 | [MOL File]
672937-63-2.mol | [Molecular Weight]
369.48 |
| Chemical Properties | Back Directory | [Melting point ]
96-97°C | [Boiling point ]
517.7±30.0 °C(Predicted) | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
Powder | [pka]
-6.63±0.70(Predicted) | [color ]
white to yellow | [Sensitive ]
air sensitive | [BRN ]
9656639 | [InChI]
1S/C23H32NOP/c1-25-22-16-9-8-15-21(22)24-18-10-17-23(24)26(19-11-4-2-5-12-19)20-13-6-3-7-14-20/h8-10,15-20H,2-7,11-14H2,1H3 | [InChIKey]
JUZAKZRALSJLOV-UHFFFAOYSA-N | [SMILES]
COc1ccccc1-n2cccc2P(C3CCCCC3)C4CCCCC4 |
| Hazard Information | Back Directory | [Chemical Properties]
White to yellow powder | [Uses]
Used as ligand in arylation reaction with bromobenzene, and phosphorylation reactions with chlorophosphines 1 Cocatalyst in palladium-catalyzed Suzuki coupling reactions 2 | [General Description]
sold in collaboration with Solvias AG | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Asymmetric synthesis |
| Questions And Answer | Back Directory | [Reaction]
- Highly efficient ligand for the palladium-catalyzed Suzuki reaction using aryl chlorides.
- Carbonylative Heck reaction of aryl bromides with vinyl ethers.
- Double carbonylation of aryl halides to synthesize 5-arylfuranones.
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