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676340-02-6

676340-02-6 Structure

676340-02-6 Structure
IdentificationBack Directory
[Name]

2H-Pyran-2-one, 6-[(3E,5E,11E)-1,3,5,7,11,13-hexamethyl-3,5,11-pentadecatrien-1-yl]-4-hydroxy-3,5-dimethyl-
[CAS]

676340-02-6
[Synonyms]

Alternapyrone
2H-Pyran-2-one, 6-[(3E,5E,11E)-1,3,5,7,11,13-hexamethyl-3,5,11-pentadecatrien-1-yl]-4-hydroxy-3,5-dimethyl-
[Molecular Formula]

C28H44O3
[MOL File]

676340-02-6.mol
[Molecular Weight]

428.65
Chemical PropertiesBack Directory
[Boiling point ]

525.0±50.0 °C(Predicted)
[density ]

0.974±0.06 g/cm3(Predicted)
[form ]

A solid
[pka]

5.82±0.50(Predicted)
Hazard InformationBack Directory
[Description]

Alternapyrone is a polyketide produced in A. oryzae heterologously expressing the A. solani-derived polyketide synthase gene alt5.
[Uses]

Alternapyrone is an α-pyrone compound found in fungi, some of which are phytotoxic to wheat seed germination, and its biosynthesis requires only three enzymes.
[Definition]

ChEBI: Alternapyrone is a member of the class of 2-pyranones that is 2H-pyran-2-one in which the hydrogens at positions 3, 4, 5 and 6 are replaced by methyl, hydroxy, methyl and (4E,6E,12E)-4,6,8,12,14-pentamethylhexadeca-4,6,12-trien-2-yl groups, respectively. It is a decaketide that is anabolized by a type I polyketide synthase in Alternaria solani. It has a role as a fungal metabolite. It is an olefinic compound, a member of 2-pyranones, a heteroaryl hydroxy compound and a decaketide.
[References]

[1] Chemical Ecogenomics-Guided Discovery of Phytotoxic α-Pyrones from the Fungal Wheat Pathogen Parastagonospora nodorum
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