| Identification | Back Directory | [Name]
TEBBE REAGENT | [CAS]
67719-69-1 | [Synonyms]
tebbe
TEBBE REAGENT
Tebbe's reagent
tebbe reagent solution
ca.0.5mol/lToluenesolution
TEBBE REAGENT, 0.5M SOLUTION IN TOLUENE
Tebbe Reagent (ca. 0.5mol/L in Toluene)
TEBBE REAGENT SOLUTION, ~0.5 M IN TOLUEN E
Tebbe reagent, 0.5M solution in toluene, SpcSeal
Tebbe reagent, 0.5M solution in toluene, AcroSeal
Chlorobishetacyclopentadienyldimethylammoniummumethyle
μ-Chloro-μ-methylenebis(cyclopentadienyl)-titaniumdimethylaluminum
M-CHLORO-M-METHYLENEBIS(CYCLOPENTADIENYL)-TITANIUMDIMETHYLALUMINUM
MU-CHLOROBIS(CYCLOPENTADIENYL)(DIMETHYLALUMINUM)-MU-METHYLENETITANIUM
MU-CHLORO-MU-METHYLENE[BIS(CYCLOPENTADIENYL)TITANIUM]DIMETHYLALUMINUM
bis(cyclopentadienyl)-μ-chloro-(dimethylaluminum)-μ-methylenetitanium
BIS(CYCLOPENTADIENYL)-MU-CHLORO(DIMETHYLALUMINUM)-MU-METHYLENETITANIUM
MU-CHLOROBIS(ETA5-CYCLOPENTADIENYL)(DIMETHYLALUMINUM)-MU-METHYLENETITANIUM
Bis(cyclopentadienyl-micron-chloro(dimethylaluminum-micron-methylenetitanium
micro-Chloro-micro-methylene [bis(cyclopentadienyl)titanium]dimethylaluminum
MU-CHLOROBIS(((ETA)5)-CYCLOPENTADIENYL)(DIMETHYLAMMONIUM)-MU-METHYLENE-TITANIUM
mu-Chlorobis(((heta)^5)-cyclopentadienyl)(dimethylammonium)-mu-methylene-titanium
μ-Chloro-μ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene
^m-Chloro-^m-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene
mu-Chloro-mu-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene
ae-chloro-ae-methylenebis(cyclopentadienyl)-titaniumdimethylaluminum, 0.5m in toluene
Titanium, .mu.-chlorobis(.eta.5-2,4-cyclopentadien-1-yl)(dimethylaluminum)-.mu.-methylene-
μ-Chloro-μ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum solution, 0.5M in toluene
MU-CHLOROBIS(ETA5-CYCLOPENTADIENYL)(DIMETHYLALUMINUM)-MU-METHYLENE-TITANIUM (CA. 0.5MOL L TOLUENE SOLN.)
mu-Chloro-mu-methylene[bis(cyclopentadienyl)titanium]dimethylaluminum
mu-Chlorobis(eta5-cyclopentadienyl)(dimethylaluminum)-mu-methylenetitanium | [Molecular Formula]
C13H18AlClTi 10* | [MDL Number]
MFCD00151575 | [MOL File]
67719-69-1.mol | [Molecular Weight]
284.58 |
| Chemical Properties | Back Directory | [Appearance]
Dark red to purple solution | [density ]
0.96 g/mL at 20 °C
| [Fp ]
34 °F
| [storage temp. ]
Refrigerator | [form ]
Solution | [color ]
Dark red to purple | [Water Solubility ]
Soluble in toluene, benzene, dichloromethane. Insoluble in water. | [Sensitive ]
Air & Moisture Sensitive | [Merck ]
9091 | [Exposure limits]
ACGIH: TWA 20 ppm
OSHA: Ceiling 300 ppm; TWA 200 ppm
NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3) | [InChI]
InChI=1S/2C5.2CH2.C.Al.ClH.Ti/c2*1-2-4-5-3-1;;;;;;/h;;2*1H2;;;1H;/q4*-1;-2;+3;;+4/p-1 | [InChIKey]
QEJAQNUJXFLWSP-UHFFFAOYSA-M | [SMILES]
[CH2-][Al+3]1([Cl-][Ti+4]23456789(C%10[C-]2C3=C4C5=%10)(C2[C-]6C7=C8C9=2)[C-2]1)[CH2-] |
| Hazard Information | Back Directory | [Chemical Properties]
Dark red to purple solution | [Uses]
Reagent for the methylenation of carbonyl groups. | [General Description]
Tebbe reagent is a Lewis acid stabilized organometallic compound, which is used to transform carbonyl groups into β-substituted methylenes. It also reacts with a wide range of carbonyl compounds, including esters, amides, and lactones to yield corresponding olefins. | [reaction suitability]
reaction type: C-C Bond Formation |
| Safety Data | Back Directory | [Hazard Codes ]
F,C | [Risk Statements ]
11-34-48/20-63-65-67 | [Safety Statements ]
26-36/37/39-45-62-16 | [RIDADR ]
UN 2924 3/PG 2
| [WGK Germany ]
2
| [F ]
1-10 | [HazardClass ]
4.3 | [PackingGroup ]
II | [HS Code ]
29310099 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Aquatic Chronic 3
Asp. Tox. 1
Eye Dam. 1
Flam. Liq. 2
Repr. 2
Skin Corr. 1B
STOT RE 2
STOT SE 3 |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
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| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
3A Chemicals
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| Telephone: |
400-668-9898 |
| Website: |
www.3achem.com |
|