| Identification | Back Directory | [Name]
1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole | [CAS]
69352-04-1 | [Synonyms]
100170
1-chloro-1,3-dihydro-3,3-dimethyl benz iodoxole
1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole
1,2-Benziodoxole, 1-chloro-1,3-dihydro-3,3-dimethyl-
1-Chloro-3,3-dimethyl-1,3-dihydro-1λ3-benzo[d][1,2]iodaoxole
1-?Chloro-?1,?3-?dihydro-?3,?3-?dimethyl-?1,?2-?benziodioxole | [Molecular Formula]
C9H10ClIO | [MDL Number]
MFCD21648251 | [MOL File]
69352-04-1.mol | [Molecular Weight]
296.53 |
| Chemical Properties | Back Directory | [Melting point ]
143-145 °C(Solv: carbon tetrachloride (56-23-5)) | [storage temp. ]
2-8°C, protect from light | [form ]
solid | [Appearance]
Light yellow to green yellow Solid | [InChI]
1S/C9H10ClIO/c1-9(2)7-5-3-4-6-8(7)11(10)12-9/h3-6H,1-2H3 | [InChIKey]
HEBYOYIIQNKPGQ-UHFFFAOYSA-N | [SMILES]
[I]1(OC(c2c1cccc2)(C)C)Cl |
| Safety Data | Back Directory | [WGK Germany ]
WGK 1 | [Storage Class]
5.1B - Oxidizing hazardous materials | [Hazard Classifications]
Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Ox. Sol. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
1-?Chloro-?1,?3-?dihydro-?3,?3-?dimethyl-?1,?2-?benziodioxole is used as a reactant in one-pot preparation of hypervalent iodine(III)-CF3 reagent for the use in electrophilic trifluoromethylation reactions. | [Uses]
1-Chloro-3,3-dimethylbenziodoxole is a crystalline, air-stable, yellow chloroiodane compound which finds use as a starting material for production of other hypervalent iodine compounds. It can also be used as a mild chlorinating reagent. The compound shows good solubility in polar organic solvents, typically dichloromethane or ethyl acetate. | [reaction suitability]
reaction type: C-C Bond Formation |
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