| Identification | Back Directory | [Name]
BIS(3,5-DIMETHYLPHENYL)PHOSPHINE | [CAS]
71360-06-0 | [Synonyms]
Bis(3,5-dimethyL
98% [(CH3)2C6H3]2PH
Bis(3,5-dimethylphenyl)
bis(3,5-dimethylphenyl)phosphane
Bis(3,5-dimethylphenyi)phosphine
BIS(3,5-DIMETHYLPHENYL)PHOSPHINE
Phosphine, bis(3,5-dimethylphenyl)-
Bis(3,5-dimethylphenyl)phosphine,99%
Bis(3,5-dimethylphenyl)phosphine, 98% (10wt% in hexanes)
Bis(3,5-diMethylphenyl)phosphine, 98% (10% solution in hexanes) | [Molecular Formula]
C16H19P | [MDL Number]
MFCD01074629 | [MOL File]
71360-06-0.mol | [Molecular Weight]
242.3 |
| Chemical Properties | Back Directory | [Boiling point ]
368.8±42.0 °C(Predicted) | [density ]
1.017 g/mL at 25 °C | [refractive index ]
n20/D1.599 | [Fp ]
>110℃ | [form ]
liquid | [color ]
colorless | [Sensitive ]
air sensitive | [InChI]
InChI=1S/C16H19P/c1-11-5-12(2)8-15(7-11)17-16-9-13(3)6-14(4)10-16/h5-10,17H,1-4H3 | [InChIKey]
GPFIUEZTNRNFGD-UHFFFAOYSA-N | [SMILES]
P(C1=CC(C)=CC(C)=C1)C1=CC(C)=CC(C)=C1 |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless liquid | [Uses]
Bis(3,5-dimethylphenyl)phosphine can be used as a reactant to prepare:
- Iron(II) chiral diimine diphosphine complexes as catalysts for the asymmetric transfer hydrogenation of ketones.
- The complex of iridium with biphenol phosphite-phosphine bidentate ligand as an asymmetric catalyst for the hydrogenation of N-arylimines.
- Chiral phosphines with excellent stereoselectivity by 1, 4 addition reaction with α,β-unsaturated aldehydes using a palladium catalyst.
| [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Aemon Chemical
|
| Telephone: |
0086-755-86198205 |
| Website: |
www.aemonchem.com |
|