| Identification | Back Directory | [Name]
Naphthalene, radical ion(1-), lithium (1:1) | [CAS]
7308-67-0 | [Synonyms]
Lithium naphthylide
Naphthalene, radical ion(1-), lithium (1:1) | [Molecular Formula]
C10H8Li+ | [MOL File]
7308-67-0.mol | [Molecular Weight]
135.11 |
| Hazard Information | Back Directory | [Chemical Properties]
Copper species generated in THF, dioxane, glyme, etc. The reagent is generated in an inert atmosphere as needed.
| [Uses]
Naphthalene, radical ion(1-), lithium (1:1) is a zerovalent copper species which adds to organic halides to produce organocopper compounds; used to cross-couple aryl, alkynyl, and vinyl halides with acid chlorides and reactive alkyl halides; to effect conjugate additions to α,β-unsaturated ketones; to promote intramolecular cyclization with epoxide cleavage or of α,ο-dihaloalkanes; to remotely functionalize esters.
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