| Identification | Back Directory | [Name]
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- | [CAS]
7428-60-6 | [Synonyms]
Tris(trimethylsilyl)silanol
Tris(trimethylsilyl)silanol >=95%
Hydroxy-tris(trimethylsilyl)silane
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- | [Molecular Formula]
C9H28OSi4 | [MDL Number]
MFCD00093727 | [MOL File]
7428-60-6.mol | [Molecular Weight]
264.66 |
| Chemical Properties | Back Directory | [Boiling point ]
235.1±23.0 °C(Predicted) | [density ]
0.833±0.06 g/cm3(Predicted) | [refractive index ]
n/D 1.496 | [storage temp. ]
2-8°C, sealed storage, away from moisture | [form ]
liquid | [pka]
15.57±0.53(Predicted) | [Appearance]
Colorless to light yellow Liquid | [InChI]
1S/C9H28OSi4/c1-11(2,3)14(10,12(4,5)6)13(7,8)9/h10H,1-9H3 | [InChIKey]
ABTWCNHNRLMBFR-UHFFFAOYSA-N | [SMILES]
[Si]([Si](C)(C)C)([Si](C)(C)C)([Si](C)(C)C)O |
| Hazard Information | Back Directory | [Uses]
Under a dual catalytic copper/photoredox manifold, this supersilanol has been demonstrated by the MacMillan lab to be an excellent reagent for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. To be use in conjunction with dMesSCF3 (901466) and Ir photocatalyst (902217 or 902225). | [reaction suitability]
reaction type: C-C Bond Formation |
|
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Energy Chemical Gold
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| Company Name: |
Energy Chemical
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| Tel: |
021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Energy Chemical
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| Tel: |
021-58432009 400-005-6266 |
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http://www.energy-chemical.com |
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