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74311-56-1

74311-56-1 Structure

74311-56-1 Structure
IdentificationBack Directory
[Name]

(R)-(S)-BPPFA
[CAS]

74311-56-1
[Synonyms]

(R)-(S)-BPPFA
(-)-(R)-(S)-BPPFA
)-(R)-N,N-Dimethyl-1-[(S)-1
(-)-(R)-N,N-dimethyl-1-((S)-1',2-bis(di-phenylpho
(R)-N,N-Dimethyl-1-((S)-1',2-bis(diphenylphosphino
N,N-dimethyl-1-[1,2-bis(diphenylphosphino)ferrocenyl]ethyl
(R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferroceny...
[r,r]-1-[1-dimethylaminoethyl]-1',2-bis[diphenylphosphino]ferrocene
(R)-N,N-DIMETHYL-1-[(S)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
(2S)-1-[(1R)-1-(Dimethylamino)ethyl]-1',2-bis(diphenylphosphino)ferrocene
(R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine>
(R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine,98%
(-)-(R)-N,N-DIMETHYL-1-[(S)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
Ferrocene,1-[(1R)-1-(dimethylamino)ethyl]-1',2-bis(diphenylphosphino)-, (2S)-
(-)-(R)-N,N-DIMETHYL-1-((S)-1',2-BIS(DI- PHENYLPHOSPHINO)FERROCENYL)ET-AMIN,95%
[Molecular Formula]

C38H37FeNP2 10*
[MDL Number]

MFCD00075284
[MOL File]

74311-56-1.mol
[Molecular Weight]

625.5
Chemical PropertiesBack Directory
[Melting point ]

143-144 °C(lit.)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2–8 °C
[form ]

solid
[color ]

Light yellow to Brown
[optical activity]

[α]20/D 350°, c = 0.5 in chloroform
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22-36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
[HS Code ]

2931.90.6000
Hazard InformationBack Directory
[Uses]

(-)-(R)-(S)-BPPFA is an electron-rich bulky ligand used in amination reactions of aryl halides and tosylates. Homogeneous catalyst.
[Uses]

Ligand used in the enantioselective silylation of allylic chlorides.
Spectrum DetailBack Directory
[Spectrum Detail]

(R)-(S)-BPPFA(74311-56-1)1HNMR
(R)-(S)-BPPFA(74311-56-1)IR
(R)-(S)-BPPFA(74311-56-1)Raman
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