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74663-77-7

74663-77-7 Structure

74663-77-7 Structure
IdentificationBack Directory
[Name]

2,3-BIS(2,6-DI-I-PROPYLPHENYLIMINO)BUTANE
[CAS]

74663-77-7
[Synonyms]

Diacetyl-bis(2,6-isopropylphenylimine)
2,3-BIS(2,6-DI-I-PROPYLPHENYLIMINO)BUTANE
2,3-BIS-(2,6-DIISOPROPYLPHENYLIMINO)BUTANE
2,3-Bis(2,6-di-i-propylphenylimino)butane,98%
2,3-Bis(2,6-diisopropylphenylimino)butane 98%
N,N'-Bis(2,6-diisopropylphenyl)-2,3-butanediimine
N,N'-Bis(2,6-diisopropylphenyl)butane-2,3-diimine
N,N'-(2,3-Butanediylidene)bis(2,6-diisopropylaniline)
N,N'-(1,2-Dimethylethane-1,2-diylidene)bis(2,6-diisopropylaniline)
N,N'-(1,2-Dimethyl-1,2-ethanediylidene)bis(2,6-diisopropylaniline)
N,N''-(1,2-Dimethyl-1,2-ethanediylidene)-bis-[2,6-bis-(1-methylethyl)-benzen
N,N'-(1,2-Dimethyl-1,2-ethanediylidene)bis[2,6-bis(1-methylethyl)benzenamine]
[Molecular Formula]

C28H40N2
[MDL Number]

MFCD01862435
[MOL File]

74663-77-7.mol
[Molecular Weight]

404.63
Chemical PropertiesBack Directory
[Melting point ]

104-106°C
[storage temp. ]

2-8°C, protect from light, stored under nitrogen
[form ]

crystal
[color ]

yellow
[BRN ]

6746881
[InChI]

InChI=1S/C28H40N2/c1-17(2)23-13-11-14-24(18(3)4)27(23)29-21(9)22(10)30-28-25(19(5)6)15-12-16-26(28)20(7)8/h11-20H,1-10H3
[InChIKey]

YUFQUBWPYIPRHZ-UHFFFAOYSA-N
[SMILES]

C(=NC1=C(C(C)C)C=CC=C1C(C)C)(C)C(=NC1=C(C(C)C)C=CC=C1C(C)C)C
Safety DataBack Directory
[Symbol(GHS) ]

GHS hazard pictograms
GHS07
[Signal word ]

Warning
[Hazard statements ]

H413
[Precautionary statements ]

P501-P273
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
[HS Code ]

2925.29.6000
[Storage Class]

13 - Non Combustible Solids
[Hazard Classifications]

Aquatic Chronic 4
Questions And AnswerBack Directory
[Reactions]

  1. 1. Ligand used in the preparation of highly active metal catalysts for the polymerization of ethylene (ref 1, M=Ni, Pd) and olefins (ref 2, M=Pd; ref 3, M= Hf, Zr)
  2. Ligand for the iron catalyzed polymerization of styrene acrylate monomers
  3. Ligand for Yttrium complex that catalysis the ring-opening polymerization of cyclic esters
  4. Ligand for rare-earth dichloro and bis(alkyl) complexes for isoprene polymerization
  5. Ligand for cobalt catalyzed alkene hydroboration
  6. Ligand for nickel catalyzed alkene hydrosilylation
Reactions of 74663-77-7
Hazard InformationBack Directory
[Uses]

Reactant for synthesis of:
  • Lanthanide(II)-alkali sandwich complexes
  • Imido-amido Hf complexes
  • Alkali metal compounds
  • Tetracoordinated molybdenum(II) complexes

Reactant for:
  • Complexation of dimethylmagnesium with α-diimines
  • Transfer of tin and germanium atoms from N-heterocyclic stannylenes and germylenes to diazadienes
[reaction suitability]

reagent type: ligand
Spectrum DetailBack Directory
[Spectrum Detail]

2,3-BIS(2,6-DI-I-PROPYLPHENYLIMINO)BUTANE(74663-77-7)1HNMR
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