| Identification | Back Directory | [Name]
1H-INDENE, 5-BROMO- | [CAS]
75476-78-7 | [Synonyms]
SKL641
5-BROMO-1H-INDENE
1H-INDENE, 5-BROMO-
5-Bromo-1H-indene 95+% | [Molecular Formula]
C9H7Br | [MDL Number]
MFCD03659729 | [MOL File]
75476-78-7.mol | [Molecular Weight]
195.06 |
| Chemical Properties | Back Directory | [Melting point ]
36 °C | [Boiling point ]
120 °C(Press: 16 Torr) | [density ]
1.523±0.06 g/cm3(Predicted) | [storage temp. ]
Store at room temperature | [Appearance]
White to off-white Solid |
| Hazard Information | Back Directory | [Synthesis]
General procedure for the synthesis of 5-bromo-1H-indene from 6-bromo-2,3-dihydro-1H-inden-1-ol: 170 g of 6-bromo-2,3-dihydro-1H-inden-1-ol, 1.2 L of hydroxybenzenesulphonic acid, p-toluenesulphonic acid, and 8 g of catalyst were added to a reaction flask for 3 hours. After completion of the reaction, benzene was removed by distillation. The crude product was purified by fast chromatography to give 148 g of 5-bromo-1H-indene (in the form of coral oil) in 95% yield. | [References]
[1] Journal of Organic Chemistry, 1984, vol. 49, # 22, p. 4226 - 4237
[2] Patent: JP2016/29040, 2016, A. Location in patent: Paragraph 0059
[3] Organic and Biomolecular Chemistry, 2003, vol. 1, # 8, p. 1298 - 1307
[4] Journal of Organic Chemistry, 1980, vol. 45, # 26, p. 5312 - 5315
[5] Bioorganic and Medicinal Chemistry Letters, 1999, vol. 9, # 12, p. 1657 - 1662 |
|
| Company Name: |
Tetranov Biopharm
|
| Tel: |
13526569071 |
| Website: |
www.leadmedpharm.com/index.html |
| Company Name: |
SynAsst Chemical.
|
| Tel: |
021-60343070 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList15848/0_EN.htm |
|