| Identification | Back Directory | [Name]
DICHLOROTITANIUM DIISOPROPOXIDE | [CAS]
762-99-2 | [Synonyms]
DICHLORO(DIISOPROPOXY)TITANIUM
DICHLOROTITANIUM DIISOPROPOXIDE
DichlorotitaniumDiisopropoxide>
dichlorobis(propan-2-olato)titanium
Titanium,dichlorobis(2-propanolato)-, (T-4)- | [EINECS(EC#)]
212-106-6 | [Molecular Formula]
C6H14Cl2O2Ti | [MDL Number]
MFCD00191416 | [MOL File]
762-99-2.mol | [Molecular Weight]
236.95 |
| Hazard Information | Back Directory | [Uses]
Dichlorotitanium diisopropoxide is a Lewis acid frequently used in the preparation of chiral titanium complexes; an efficient catalyst for Diels-Alder reactions, [2 + 2] cycloadditions, and carbonyl-ene reactions, including asymmetric versions of these processes; a reagent for titanium enolate formation; and a catalyst component for the stereoselective addition of cyanide and allyltin nucleophiles to aldehydes. | [Preparation]
Dichlorotitanium diisopropoxide is prepared by adding slowly at rt an equimolar amount of Titanium(IV) Chloride to a hexane solution of Titanium Tetraisopropoxide; following mixing, during which heat is evolved, the mixture is allowed to stand at rt for 6 h and the precipitate is collected and washed with hexane; dibromotitanium diisopropoxide is prepared similarly. | [storage]
Corrosive; moisture sensitive; use in a fume hood; can be stored under nitrogen in pure form or in solution. |
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| Company Name: |
Energy Chemical
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http://www.energy-chemical.com |
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TCI Europe
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320-37350700 |
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https://www.tcichemicals.com/de/de/index.html |
| Company Name: |
TCI AMERICA
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800-4238616 |
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