| Identification | Back Directory | [Name]
BENZYLDIPHENYLPHOSPHINE | [CAS]
7650-91-1 | [Synonyms]
BENZYLDIPHENYLPHOSPHINE
Diphenylbenzylphosphine
Benzyldiphenylphosphine,97%
Benzyldiphenylphosphine,98%
Benzyldiphenylphosphine,99%
Diphenyl(phenylmethyl)phosphine | [EINECS(EC#)]
1312995-182-4 | [Molecular Formula]
C19H17P | [MDL Number]
MFCD00014083 | [MOL File]
7650-91-1.mol | [Molecular Weight]
276.31 |
| Chemical Properties | Back Directory | [Appearance]
White to off-white powder | [Melting point ]
77-83 °C(lit.)
| [Boiling point ]
205-208 °C(Press: 1.5 Torr) | [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
Powder | [color ]
White to off-white | [Water Solubility ]
Slightly soluble in water. | [Sensitive ]
Air Sensitive | [InChI]
InChI=1S/C19H17P/c1-4-10-17(11-5-1)16-20(18-12-6-2-7-13-18)19-14-8-3-9-15-19/h1-15H,16H2 | [InChIKey]
UZCPNEBHTFYJNY-UHFFFAOYSA-N | [SMILES]
P(C1=CC=CC=C1)(C1=CC=CC=C1)CC1=CC=CC=C1 |
| Hazard Information | Back Directory | [Chemical Properties]
White to off-white powder | [Uses]
suzuki reaction | [Preparation]
An acetato-bridged binuclear cyclopalladated complex of benzyldiphenylphosphine, [{Pd(C6H4CH2PPh2)(O2CMe)}], could been obtained by the reaction between the phosphine and palladium(II) acetate[1]. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings | [References]
[1] Katsuma Hiraki, Toshinobu Uchiyama, Yoshio Fuchita. “Cyclopalladation of benzyldiphenylphosphine by palladium(II) acetate.” Inorganica Chimica Acta 69 (1983): Pages 187-190.
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