| Identification | Back Directory | [Name]
1-BROMO-4-(PENTAFLUOROSULFANYL)BENZENE | [CAS]
774-93-6 | [Synonyms]
4-BROMOPHENYL-PENTAFLUOROSULFUR
4-Pentafluorosulfur bromobenzene
4-BROMOPHENYLSULFUR PENTAFLUORIDE
p-Bromophenylsulfur Pentafluoride
1-BROMO-4-(PENTAFLUOROTHIO)BENZENE
4-BROMOPHENYLSULPHUR PENTAFLUORIDE
(4-Bromophenyl)pentafluoro-l6-sulfane
4-Bromophenylsulfur Pentafluoride >
1-BROMO-4-(PENTAFLUOROSULFANYL)BENZENE
4-BroMophenylsulfur pentafluoride, 95+%
(OC-6-21)-(4-Bromophenyl)pentafluorosulfur
(4-bromophenyl)-pentafluoro-lambda6-sulfane
Sulfur, (4-bromophenyl)pentafluoro-, (OC-6-21)-
Sulfur,(4-broMophenyl)pentafluoro-, (OC-6-21)- (9CI)
1-Bromo-4-(pentafluorothio)benzene, 1-Bromo-4-(pentafluorosulphanyl)benzene | [Molecular Formula]
C6H4BrF5S | [MDL Number]
MFCD03425928 | [MOL File]
774-93-6.mol | [Molecular Weight]
283.06 |
| Chemical Properties | Back Directory | [Boiling point ]
77.2 °C(Press: 10 Torr) | [refractive index ]
1.4790-1.4830 | [Fp ]
84°C(lit.) | [storage temp. ]
0-10°C | [form ]
liquid | [color ]
Clear, colourless | [InChI]
InChI=1S/C6H4BrF5S/c7-5-1-3-6(4-2-5)13(8,9,10,11)12/h1-4H | [InChIKey]
RECCABBXFXGELM-UHFFFAOYSA-N | [SMILES]
S(F)(F)(F)(F)(F)C1=CC=C(Br)C=C1 |
| Hazard Information | Back Directory | [Synthesis]
5.0 g of 4-pentafluorosulfanylaniline was dissolved in 20 ml of acetic acid, and, at 0 ℃, a saturated aqueous HBr solution was added. Then, at 0 ℃, a solution of 1.9 of NaNO2 in 5 ml of water was slowly added dropwise over the course of 5 minutes. The reaction mixture was stirred at 0 C. for 10 minutes and then added in portions to a suspension of 6.5 g of CuBr in 20 ml of a half-saturated aqueous HBr solution at 0 ℃. Nitrogen is liberated during this. The mixture was stirred at 0 ℃. for 30 minutes and then at RT for 1 h. It was subsequently extracted 3 times with 100 ml of HEP each time, and then the HEP was washed twice with 50 ml of a saturated aqueous Na2CO3 solution each time. The residue, after drying over MgSO4 and removal of the solvent in vacuo, was chromatographed on silica gel with HEP. 1.8 g of a colorless oil 1-Bromo-4-(pentafluorosulfanyl)benzene were obtained. |
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| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|