| Identification | Back Directory | [Name]
1,3-Dimethyl-1-(trimethylsilyl)allene | [CAS]
77494-35-0 | [Synonyms]
2-(Trimethylsilyl)-2,3-pentadiene
1,3-Dimethyl-1-(trimethylsilyl)allene
Silane, trimethyl(1-methyl-1,2-butadien-1-yl)- | [Molecular Formula]
C8H16Si | [MDL Number]
MFCD17171289 | [MOL File]
77494-35-0.mol | [Molecular Weight]
140.3 |
| Chemical Properties | Back Directory | [density ]
0.746 g/mL at 25 °C | [refractive index ]
n20/D1.444 | [Fp ]
-9℃ | [storage temp. ]
-20°C | [form ]
liquid | [InChI]
1S/C8H16Si/c1-6-7-8(2)9(3,4)5/h6H,1-5H3 | [InChIKey]
JGOGDIIEKVYPFO-UHFFFAOYSA-N | [SMILES]
CC=C=C(C)[Si](C)(C)C |
| Safety Data | Back Directory | [Hazard Codes ]
F | [Risk Statements ]
11 | [Safety Statements ]
16 | [RIDADR ]
UN 1993BF 3 / PGII | [WGK Germany ]
3 | [Storage Class]
3 - Flammable Liquids | [Hazard Classifications]
Flam. Liq. 2 |
| Hazard Information | Back Directory | [Uses]
Reactant for:
- Oxidative cyclization with chlorine to give chloro- and acetoxybenziodoxaboroles and a self-assembled tetrameric macrocyclic structure
- Preparation of allylic alcohols or enone derivatives using boronic acid as catalyst
Catalyst for:
- Preparation of acylsulfoximines via N-acylation of sulfoximines with aliphatic acids
- Direct amide bond formation
- Regioselective preparation of substituted triazole derivatives via dipolar cycloaddition of unsaturated carboxylic acids with azides
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Sigma-Aldrich
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https://www.sigmaaldrich.cn |
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