| Identification | Back Directory | [Name]
1-CHLOROETHYLTRIMETHYLSILANE | [CAS]
7787-87-3 | [Synonyms]
1-CHLOROETHYLTRIMETHYLSILANE (1-chloroethyl)trimethyl-silan alpha-Chloroethyltrimethylsilane Silane, (1-chloroethyl)trimethyl- 1-Chloroethyltrimethylsilane(tech.) | [EINECS(EC#)]
232-135-8 | [Molecular Formula]
C5H13ClSi | [MDL Number]
MFCD00042611 | [MOL File]
7787-87-3.mol | [Molecular Weight]
136.7 |
| Chemical Properties | Back Directory | [Boiling point ]
116 °C (lit.) | [density ]
0.864 g/mL at 20 °C (lit.) | [refractive index ]
n20/D 1.422 | [Fp ]
20°C | [form ]
liquid | [Specific Gravity]
0.964 | [Hydrolytic Sensitivity]
4: no reaction with water under neutral conditions | [BRN ]
1732094 | [InChI]
1S/C5H13ClSi/c1-5(6)7(2,3)4/h5H,1-4H3 | [InChIKey]
UWJVDEZZIPJQRF-UHFFFAOYSA-N | [SMILES]
CC(Cl)[Si](C)(C)C | [EPA Substance Registry System]
Silane, (1-chloroethyl)trimethyl- (7787-87-3) |
| Safety Data | Back Directory | [Hazard Codes ]
F | [Risk Statements ]
11 | [Safety Statements ]
16-23-24/25 | [RIDADR ]
UN 1993 3/PG 2 | [WGK Germany ]
3 | [TSCA ]
Yes | [HazardClass ]
3.1 | [PackingGroup ]
II | [HS Code ]
2931900090 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Eye Irrit. 2 Flam. Liq. 2 Skin Irrit. 2 STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
(1-Chloroethyl)trimethylsilane can be used as textile scouring agents. | [Preparation]
α-lithio derivative prepared from 1-chloroethyltrimethylsilane in THF and s-butyllithium (1.5 M in n-hexane or cyclohexane) at -78 °C, followed by warming to -55 °C[1]. | [References]
1. Cooke, F.; Roy, G.; Magnus, P. OM 1982, 1, 893. |
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Sigma-Aldrich
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