| Identification | Back Directory | [Name]
bis(acetonitrile)chloronitrilepalladium(II) | [CAS]
77933-52-9 | [Synonyms]
bis(acetonitrile)chloronitrilepalladium(II)
Bis(acetonitrile)chloronitropalladium(II)
| [MDL Number]
MFCD00151648 | [MOL File]
77933-52-9.mol |
| Hazard Information | Back Directory | [Uses]
bis(acetonitrile)chloronitrilepalladium(II) is a reagent capable of catalyzing the oxidation of alkenes to ketones, aldehydes, or epoxides. | [Preparation]
bis(acetonitrile)chloronitrilepalladium(II) can be prepared from the reaction of Pd(MeCN)2Cl2 (formed from Palladium(II) Chloride and acetonitrile) with 1 equiv of Silver(I) Nitrite in Acetonitrile. Removal of the silver chloride after 1 h by filtration and evaporation of the solvent gives the required complex in quantitative yield. | [storage]
bis(acetonitrile)chloronitrilepalladium(II) should be stored under an inert atmosphere. Palladium compounds are reported to be mildly toxic. Acetonitrile is highly flammable and lachrymatory. |
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