| Identification | Back Directory | [Name]
DIOXATHION | [CAS]
78-34-2 | [Synonyms]
Delcar
AC 528
co-nav
Delnav
Deltic
Kavadel
Navadel
Delnav I
Delnatex
Delnav II
Dioxation
ENT 22897
ent22,897
DELNAV(R)
DIOXATHION
NAVADEL(R)
Dioxothion
ENT 22,897
NCI-C00395
DIOXATHIONE
HERCULES 528
herculesac528
Hercules ac528
dioxanephosphate
Dioxathion (ISO)
Dioxane phosphate
DIOXATHION, 100MG, NEAT
delnav (former ussr,turkey)
Dioxathion Solution, 100ppm
dioxathion (ansi,bsi,iso,esa)
p-dioxane-2,3-diylethylphosphorodithioate
p-Dioxane-2,3-diyl ethyl phosphorodithioate
2,3-Bis(diethoxyphosphinothioylthio)-1,4-dioxane
2,3-p-dioxan-s,s’-bis(o,o-diaethyldithiophosphat)
2,3-P-Dioxan-S,S'-bis(O,O-diaethyldithiophosphat)
1,4-Diossan-2,3-diyl-bis(O,O-dietil-ditiofosfato)
1,4-Dioxaan-2,3-diyl-bis(O,O-diethyl-dithiofosfaat)
2,3-p-dioxanes,s-bis(o,o-diethylphosphorodithioate)
2,3-p-Dioxane S,S-bis(O,O-diethylphosphoroithioate)
2,3-p-Dioxane S,S-bis(O,O-diethylphosphorodithioate)
1,4-Dioxan-2,3-diyl-bis(O,O-diaethyl-dithiophosphat)
S,S'-P-DIOXANE-2,3-BIS[O,O-DIETHYL PHOSPHORODITHIOATE]
2,3-p-Dioxane S,S'-bis(O,O-diethyl phosphorodithioate)
1,4-Dioxan-2,3-diyl bis(O,O-diethyl phosphorodithioate)
2,3-p-dioxandithiols,s-bis(o,o-diethylphosphorodithioate)
2,3-p-dioxanedithiols,s-bis(o,o-diethylphosphorodithioate)
1,4-dioxaan-2,3-diyl-bis(o,o-diethyl-dithiofosfaat)[dutch]
1,4-dioxan-2,3-diylbis(o,o-diethylphosphorothiolothionate)
1,4-diossan-2,3-diil-bis(o,o-dietil-ditiofosfato)[italian]
2,3-p-Dioxandithiol S,S-bis(O,O-diethyl phosphorodithioate)
1,4-dioxan-2,3-diyl-bis(o,o-diethylphosphorothiolothionate)
2,3-p-Dioxanedithiol S,S-bis(O,O-diethyl phosphorodithioate)
1,4-dioxan-2,3-diyl-bis(o,o-diaethyl-dithiophosphat)[german]
1,4-Dioxan-2,3-Diyl bis(O,O-diethyl phosphorothiolothionate)
1,4-dioxan-2,3-diylo,o,o’,o’-tetraethyldi(phosphoromithioate)
1,4-dioxan-2,3-diylo,o,o’,o’,-tetraethyldi(phosphorodithioate)
1,4-dioxane-2,3-diyl O,O,O,O-tetraethyl di(phosphorodithioate)
1,4-Dioxan-2,3-diyl O,O,O',O'-tetraethyl di(phosphoromithioate)
bis(dithiophosphatedeo,o-diethyle)des,s’-(dioxanne-1,4diyle-2,3)
bis(dithiophosphatedeo,o-diethyle)des,s’-(1,4-dioxanne-2,3-diyle)
p-dioxane-2,3-dithiol,s,s-diesterwitho,o-diethylphosphorodithioate
[(1,4-Dioxane-2,3-diyl)bisthio]bis(thiophosphonic acid O,O-diethyl)
S,S'-(P-DIOXANE-2,3-DIYL)O,O,O',O'-TETRAETHYL DI(PHOSPHORODITHIOATE)
S,S'-(1,4-DIOXANE-2,3-DIYL)O,O,O',O'-TETRAETHYL DI(PHOSHORODITHIOATE)
Bis(dithiophosphate de O,O-diethyle) de S,S'-(1,4-dioxanne-2,3-diyle)
phosphorodithioicacid,s,s’-p-dioxane-2,3-diylo,o,o’,o’-tetraethylester
phosphorodithioicacids,s’-1,4-dioxane-2,3-diylo,o,o’o’-tetraethylester
p-Dioxane-2,3-dithiol, S,S-diester with O,O-diethyl phosphorodithioate
phosphorodithioicacid,s,s’-1,4-dioxane-2,3-diylo,o,o’,o’-tetraethylester
bis(dithiophosphatedeo,o-diethyle)des-s’(1,4-dioxanne-2,3-diyle)[french]
Phosphorodithioic acid, S,S'-p-dioxane-2,3-diyl O,O,O',O'-tetraethyl ester
Phosphorodithioic acid, S,S'-1,4-dioxane-2,3-diyl O,O,O',O'-tetraethyl ester
dioxathion (ISO) 1,4-dioxan-2,3-diyl-O,O,O',O'-tetraethyl di(phosphorodithioate)
[[3-(diethoxythiophosphorylthio)-1,4-dioxan-2-yl]thio]-diethoxy-thioxo-phosphorane
(3-diethoxyphosphinothioylsulfanyl-1,4-dioxan-2-yl)sulfanyl-diethoxy-sulfanylidene-$l^{5}-phosphane
A mixture consisting essentially of cis- and trans-S,S'-5,5'-p-dioxane-2,3-diyl bis(O,O-diethyl phosphorodithioate) | [EINECS(EC#)]
201-107-7 | [Molecular Formula]
C12H26O6P2S4 | [MDL Number]
MFCD00055335 | [MOL File]
78-34-2.mol | [Molecular Weight]
456.54 |
| Chemical Properties | Back Directory | [Appearance]
dark amber viscous liquid | [Melting point ]
-20° | [Boiling point ]
240°C (estimate) | [density ]
d426 1.257 | [refractive index ]
nD20 1.5420 | [storage temp. ]
0-6°C | [form ]
liquid | [Stability:]
Stable. Incompatible with strong acids, alkalies. May react with iron or tin. | [EPA Substance Registry System]
Dioxathion (78-34-2) |
| Hazard Information | Back Directory | [Chemical Properties]
dark amber viscous liquid | [Uses]
Insecticide; acaricide. | [General Description]
Tan liquid (technical grade is brown). Used for the control of insects and mites on grapes, citrus, walnuts, ornamentals, apples, pears, and quince. Also used as a spray or dip for the control of ticks, lice, hornfly, and sheep ked on cattle, goats, sheep, and hogs. | [Air & Water Reactions]
Insoluble in water. DIOXATHION is stable in water at a neutral pH. | [Reactivity Profile]
DIOXATHION is heat sensitive. DIOXATHION may react with iron or tin surfaces. DIOXATHION may be hydrolyzed by strong acids or alkalis. . Organophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides. | [Health Hazard]
Very toxic. Probable oral lethal dose for humans is 50-500 mg/kg or between 1 teaspoonful and 1 oz. for a 70 kg (150 lb.) person. It is a cholinesterase inhibitor. Death is primarily due to respiratory arrest arising from failure of the respiratory center, paralysis of respiratory muscles, intense bronchoconstriction, or all three. | [Fire Hazard]
Shock can shatter container, releasing contents. (Non-Specific -- Organophosphorus Pesticide, Liquid, n.o.s.) Container may explode in heat of fire. Fire may produce irritating or poisonous gases. Runoff from fire control water may give off poisonous gases. Runoff from fire control or dilution water may cause pollution. When heated to decomposition, DIOXATHION emits highly toxic fumes of oxides of nitrogen, phosphorus, and sulfur. Avoid alkali materials and heat. DIOXATHION is unstable to iron or tin surfaces and when mixed with certain carriers. | [Description]
Dioxathion is a viscous, reddish-brown liquidor powder with a garlic-like odor. Technical product is amixture of cis- and trans-isomers. Molecularweight= 456.56; Boiling point = (decomposes).135℃;Freezing/Melting point = 220℃. Hazard Identification(based on NFPA-704 M Rating System): Health 3,Flammability 1, Reactivity 0. Insoluble in water. | [Definition]
ChEBI: Dioxation is a member of dioxanes. | [Potential Exposure]
AgriculturalChemical; Tumorigen, Mutagen; Human Data. Thoseinvolved in the manufacture, formulation, or application ofthis insecticide and acaricide for control of insects andmites on grapes, citrus, etc. | [First aid]
If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Speed in removing material from skinis of extreme importance. Shampoo hair promptly if contaminated. Seek medical attention immediately. If thischemical has been inhaled, remove from exposure, beginrescue breathing (using universal precautions, includingresuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.Effects may be delayed; medical observation is recommended. Obtain authorization and/or further instructionsfrom the local hospital for administration of an antidote orperformance of other invasive procedures. | [storage]
Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, wellventilated area. | [Shipping]
Dioxathion requires a “POISONOUS/TOXICMATERIALS” label. They fall in Hazard Class 6.1 and inPacking Group II. This chemical is a regulated marinepollutant. | [Incompatibilities]
Incompatible with strong acids.Decomposes above 135℃, forming toxic oxides of phosphorus and sulfur. Attacks iron and tin surfaces.Hydrolyzed by alkalies. Dioxathion is hydrolyzed by strongbases; attacks iron and tin surfaces. Strong oxidizers maycause release of toxic phosphorus oxides.Organophosphates, in the presence of strong reducingagents such as hydrides, may form highly toxic and flammable phosphine gas. Keep away from alkaline materials. |
| Safety Data | Back Directory | [Hazard Codes ]
T+,N | [Risk Statements ]
24-26/28-50/53 | [Safety Statements ]
28-36/37-45-60-61 | [RIDADR ]
3018 | [RTECS ]
TE3350000 | [HazardClass ]
6.1(a) | [PackingGroup ]
I | [HS Code ]
29329990 | [Safety Profile]
Poison by ingestion,
inhalation, skin contact, and intraperitoneal
routes. Mutation data reported. A
cholinesterase inhibitor. When heated to
decomposition it emits very toxic fumes of
POx, and SOx,. See also PARATHION | [Hazardous Substances Data]
78-34-2(Hazardous Substances Data) | [Toxicity]
LD50 in female, male rats (mg/kg): 23, 43 orally; 63, 235 dermally (Gaines) |
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