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80049-61-2

80049-61-2 Structure

80049-61-2 Structure
IdentificationBack Directory
[Name]

TRIS(ACETONITRILE)CYCLOPENTADIENYLRUTHENIUM(II) HEXAFLUOROPHOSPHATE
[CAS]

80049-61-2
[Synonyms]

TRIS(ACETONITRILE)CYCLOPENTADIENYLRUTHE&
Tris(acetonitrile)cyclopentadienylruthenium(II)
Tris(acetonitrile)cyclopentadienylrutheniuM(II) hexafluoroph
Trisacetonitrilecyclopentadienylrutheniumhexachlorophosphate
Tris(acetonitrile)cyclopentadienylruthenium hexafluorophosphate
(Cyclopentadienyltris(acetonitrile)ruthenium hexafluorophosphate
TRIS(ACETONITRILE)CYCLOPENTADIENYLRUTHENIUM(I)HEXAFLUOROPHOSPHATE
TRIS(ACETONITRILE)CYCLOPENTADIENYLRUTHENIUM(I) HEXACHLOROPHOSPHATE
TRIS(ACETONITRILE)CYCLOPENTADIENYLRUTHENIUM(II) HEXAFLUOROPHOSPHATE
Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate,98%
Tris(acetonitrile)cyclopentadienylruthenium(II)hexafluorophosphate,min.98%
Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate, min. 98%
[Molecular Formula]

C11H14F6N3PRu 5*
[MDL Number]

MFCD02684569
[MOL File]

80049-61-2.mol
[Molecular Weight]

434.28
Chemical PropertiesBack Directory
[Appearance]

Yellow to orange or brown powder
[Melting point ]

117-118°C
[storage temp. ]

Refrigerator (+4°C)
[form ]

Powder
[color ]

Yellow to orange or brown
[Sensitive ]

Air & Moisture Sensitive
[InChI]

1S/C5H5.3C2H3N.F6P.Ru/c1-2-4-5-3-1;3*1-2-3;1-7(2,3,4,5)6;/h1-5H;3*1H3;;/q;;;;-1;+1
[InChIKey]

HJQVFVSAQOQXRG-UHFFFAOYSA-N
[SMILES]

[Ru+].CC#N.CC#N.CC#N.[CH]1[CH][CH][CH][CH]1.F[P-](F)(F)(F)(F)F
Hazard InformationBack Directory
[Chemical Properties]

Yellow to orange or brown powder
[Uses]

Tris(acetonitrile)cyclopentadienylruthenium(II) Hexafluorophosphate is a catalyst, and catalyzes the reaction of diynes with aldehydes and N,N-dimethylformamide and also catalyzes other organic reactions.
[reaction suitability]

core: ruthenium
reagent type: catalyst
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

20/21/22-36/37/38
[Safety Statements ]

22-36/37/39-26
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

28439090
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Questions And AnswerBack Directory
[Reaction]

  1. Catalyst used for the coupling of allene with activated olefines to form 1,3-diene.
  2. Catalyst used for the dimerization of propargyl alcohols.
  3. Catalyst used in the Trost's ruthenium-catalyzed ene-yne cross-coupling reaction.
  4. Catalyst for asymmetric cyclization of ω-hydroxy allyl alcohols to give α-alkenyl cyclic ethers.
  5. Catalyst for synthesis of furans from bis(alkynes) and DMSO.
Reactions of 80049-61-2_1
Reactions of 80049-61-2_2
Spectrum DetailBack Directory
[Spectrum Detail]

TRIS(ACETONITRILE)CYCLOPENTADIENYLRUTHENIUM(II) HEXAFLUOROPHOSPHATE(80049-61-2)1HNMR
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