ChemicalBook--->CAS DataBase List--->8008-57-9

8008-57-9

8008-57-9 Structure

8008-57-9 Structure
IdentificationBack Directory
[Name]

Orange sweet oil
[CAS]

8008-57-9
[Synonyms]

D05186
5-Fold
7-Fold
10 Fold)
SINENSAL
oils,orange
Orangeleafoil
Orange Brazil
Oilsweetorange
Citrus sinensis
TAROCCOORANGEOIL
oilofsweetorange
Orange sweet oil
Lemon Oil 2-Fold
Oils,orange,sweet
Nerolioil,pommade
CitrussinensisOil
ORANGEOILRESIDUES
Absolutepetitgrain
neatoilofsweetorange
Orangeoilconcentrate
Orange oil (jp15/nf)
Orange essential oil
Absoluteorangeflower
Oil ofOrange Flowers
Orange oil expressed
Orange:Sweetorangeoil
Absoluteorangeflowers
coldpressed,Season2006
Sweetorangeessentialoil
Petitgraincitronnieroil
Orangesweetoil,expressed
Orangeoil,sweet,expressed
Orangeflowerwaterabsolute
Orange peel sweet extract
Sweetorangeoil,terpeneless
Orange sweet oil USP/EP/BP
Orangeflowerwater,absolute
OIL ORANGE VALENCIA 5 FOLD
Orange peel oil terpeneless
Citrus sinensis peel extract
CALIFORNIAEXPRESSEDORANGEOIL
Absoluteorangeflowerdecoloree
Absoluteorangeflowerfromwater
OIL OF ORANGE, BITTER ITALIAN
sweet orange peel oil c.p. italy
sweet orange peel oil c.p. spain
ORANGE(CITRUSAURANTIUMDULCIS)OIL
Sweeet orange oil (cold pressed)
sweet orange peel oil c.p. brazil
sweet orange peel oil decolorized
sweet orange peel oil c.p. florida
Citrus Aurantium Dulcis Flower Oil
sweet orange peel oil c.p. valencia
sweet orange peel oil folded brazil
sweet orange peel oil folded florida
Citrus aurantium, Citrus sinensis
Petitgrainbigaradesurfleursd’oranger
Sweet orange oil/Orange essential oil
sweet orange peel oil folded valencia
sweet orange peel oil c.p. california
sweet orange peel oil c.p. west indian
sweet orange peel oil c.p. french guinea
CITRUS AURANTIUM DULCIS (ORANGE) PEEL OIL
Citrus aurantium, Citrus sinensis, Orange oil
China factory supply Orange sweet oil CAS 8008-57-9
ORANGE PEEL OIL, SWEET (CITRUS SINENSIS (L.) OSBECK)
ORANGE OIL TERPENELESS (CITRUS SINENSIS (L.) OSBECK)
Citrus aurantium, Citrus sinensis, ex Orange, Orange oil
China factory supply Orange sweet oil CAS 8008-57-9 with Best Price
[EINECS(EC#)]

933-127-3
[Molecular Formula]

C15H24O
[MDL Number]

MFCD00284020
Chemical PropertiesBack Directory
[Boiling point ]

177 °C
[density ]

0.845 g/mL at 25 °C
[FEMA ]

2822 | ORANGE OIL TERPENELESS (CITRUS SINENSIS (L.) OSBECK)
[refractive index ]

n20/D 1.473
[Fp ]

130 °F
[color ]

Yellow to deep-orange liquid
[Odor]

characteristicorange and odor
[Odor Type]

citrus
[optical activity]

[α]20/D +97°, neat
[CAS DataBase Reference]

8008-57-9
[EPA Substance Registry System]

Oils, orange, sweet(8008-57-9)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

10-38
[Safety Statements ]

16-37
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

2
[RTECS ]

RI8600000
[HazardClass ]

3.2
[PackingGroup ]

III
[Safety Profile]

A skin irritant. Questionable carcinogen with experimental neoplastigenic data. When heated to decomposition it emits acrid smoke and irritating fumes.
[Hazardous Substances Data]

8008-57-9(Hazardous Substances Data)
[Toxicity]

skn-rbt 500 mg/24H MOD FCTXAV 12,733,74
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

Nerolidol-->alpha-Terpinene-->ORANGE OIL
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Orange sweet oil(8008-57-9).msds
Hazard InformationBack Directory
[Description]

Sweet orange is an evergreen tree of Oriental origin, 4 to 6 m (13 to 20 ft.) high. It has a cylindrical trunk, alternate leaves, and odorous flowers and fruits. The fruit has a green epicarp that turns yellow on ripening; a white, spongy mesocarp; and an endocarp consisting of succulent segments bearing seeds.
The Mediterranean countries in which it is cultivated include Italy (Sicily, Calabria, and Campania), Algeria, Tunisia, Morocco, Spain, and Israel; in addition, very important production occurs in California and Florida. It has an enormous worldwide economic importance. In the various countries, cultivation is geared toward the production of (1) fruits for immediate consumption and (2) fruits to be used for the production of juices or essential oils. For this purpose, the most suitable varieties have been selected.
The parts used are the leaves (and small twigs), flowers, ripe fruits, small, whole, unripe fruits, peels, and juice. The oils and various derivatives from orange, sweet have a mild to highly bitter, astringent flavor and a characteristic aroma. The juices are sweet and acidic or tart.
Petitgrain essential oil of sweet orange can be obtained from the leaves, small, whole unripe fruits, twigs, and flowers by steam distillation. Its production is low because of its limited application (perfumery).
Sweet orange essential oil is extracted from the peels of partially ripened fruits in 0.4 to 0.5% yields using suitable machinery fpr the rupturing of the oil-bearing cells (expression). A less valuable quality of essential oil is obtained by steam distillation of peels.
[Chemical Properties]

From leaves; small, whole, unripe fruits; twigs; and flowers: Petitgrain oil of sweet orange can be obtained from the above by steam distillation. Its production is low because of its limited application (perfumery). From fruit (peels): Sweet orange essential oil is extracted from peels of partially ripened fruits in 0.4 to 0.5% yields using suitable machinery for the rupturing of the oil-bearing cells (expression). A less valuable quality of essential oil is obtained by steam distillation of peels. Sweet orange oil has a characteristic odor and typical aromatic flavor. The cold-pressed sweet orange oil is obtained by expression, without the use of heat, from the fresh peel of the ripe fruit. It has a characteristic odor and taste of the outer part of fresh, sweet orange peel.
[Chemical Properties]

Sweet orange oil is obtained from the peel of the fruits of Citrus sinensis (L.)Osbeck. It is a yellow to reddish-yellow liquid with the characteristic odor of orange peel and may become cloudy when chilled. Sweet orange oil is often produced in combination with orange juice (mainly in the United States and in Brazil and, much smaller quantities, also in Spain and Israel).
d2020 0.842–0.850; n20D 1.4700–1.4760; α20D +94 ° to +99 °; evaporation residue: 1–4%.
The oils have a high terpene monoterpene hydrocarbon content. The main constituent is (+)-limonene (93–96%). Important for the typical sensory properties are components present only in low concentrations such as octanal (0.1–0.4%), decanal (0.1–0.7%), and citral (0.08–0.3%). The sesquiterpene aldehydes α-sinensal and β-sinensal (0.01–0.06%), which contribute particularly to the special sweet orange aroma, also occur in other citrus oils, although in lower concentrations. A number of higher boiling point, nonvolatile constituents contributing to the flavor and color of orange oil have been described in the literature.
Worldwide production of cold-pressed orange oil exceeds 50 000 t/yr. The main producer is Brazil (30 000 t), followed by the United States (20 000 t). The main uses of orange oil are the flavoring of beverages and confectioneries and perfuming eau de cologne, soaps, and household products.
[Physical properties]

Sweet orange essential oil is a clear, mobile liquid, with a yellow-to-orange color. The coldpressed oil is miscible with dehydrated alcohol and carbon disulfide. It is soluble in glacial acetic acid. The oil may contain a suitable antioxidant. Physical–chemical characteristics of the oil vary according to origin.
[Occurrence]

Found in the peel of the fruit Citrus sinensis (Linn.) Osbeck (Fam. Rutaceae) (Gildemeister & Hoffman, 1959; Guenther, 1949).
[Definition]

Extractives and their physically modified derivatives. Citrus sinensis, dulces, Citrus.
[Preparation]

By expression of the peel of the ripe fruit (Arctander, 1960).
[Essential oil composition]

The essential oil contains more than 90% limonene, in addition to aldehydes (decylic, octylic, nonylic and dodecylic), citral acids and esters. From the raw essence of sweet orange, the terpeneless essence can be obtained by vacuum distillation (with heat), by chromatographic separation or by extraction with low-proof alcohol. By washing the oil with low-proof alcohol, one obtains the soluble essence of sweet orange with yields of 1:50, 1:100, 1:200, 1:400; the essence is used in the flavoring of carbonated beverages, syrups, liqueurs, aperitifs and other products. Orange pastes for use in carbonated beverages are prepared using terpeneless essential oil, juices, pectins and sugars (Burdock, 1997).
Spectrum DetailBack Directory
[Spectrum Detail]

Orange sweet oil(8008-57-9)IR
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