| Identification | Back Directory | [Name]
S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-1-PHENYLETHYLAMINE | [CAS]
81510-19-2 | [Synonyms]
S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-1-PHENYLETHYLAMINE
(s)-(-)-n,n-bis(2-diphenylphosphinoethyl)-α-methylbenzylamine
S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-ALPHA-METHYLBENZYLAMINE
Benzenemethanamine, N,N-bis[2-(diphenylphosphino)ethyl]-α-methyl-, (S)- (9CI) | [Molecular Formula]
C36H37NP2 | [MDL Number]
MFCD00233840 | [MOL File]
81510-19-2.mol | [Molecular Weight]
545.63 |
| Chemical Properties | Back Directory | [Melting point ]
63-65 °C | [Boiling point ]
632.8±45.0 °C(Predicted) | [form ]
solid | [pka]
7.82±0.50(Predicted) | [Optical Rotation]
[α]20/D 4.5±0.7°, c = 1% in acetone | [BRN ]
4608384 | [InChIKey]
ZVNAHLJBPYKGBV-HKBQPEDESA-N | [SMILES]
C[C@H](N(CCP(c1ccccc1)c2ccccc2)CCP(c3ccccc3)c4ccccc4)c5ccccc5 |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
34 | [Safety Statements ]
26-36/37/39-45 | [RIDADR ]
UN 3259 8/PG 3 | [WGK Germany ]
3 | [F ]
1-10 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Eye Dam. 1
Skin Corr. 1B |
| Hazard Information | Back Directory | [Uses]
(S)-(−)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine is a chiral ligand used to prepare its iridium complexes, applicable in the synthesis of allylic alcohols via reduction of α,β-unsaturated ketones. | [General Description]
(S)-(?)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine is a chiral ligand used to prepare its iridium complexes, applicable in the synthesis of allylic alcohols via reduction of α,β-unsaturated ketones. |
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