| Identification | Back Directory | [Name]
ACETOXIME O-(2,4,6-TRIMETHYLPHENYLSULFONATE) | [CAS]
81549-07-7 | [Synonyms]
Acetoximetrimehylphenylsulfonate
O-(2,4,6-TRIMETHYLPHENYLSULFONYL)ACETOXIME
Acetoxime O-(2,4,6-trimehylphenylsulfonate)
ACETOXIME O-(2,4,6-TRIMETHYLPHENYLSULFONATE)
ACETONE O-(2,4,6-TRIMETHYLPHENYLSULFONYL)OXIME
Acetoxime O-(2,4,6-Trimethylphenylsulfonate) >
Acetoxime O-(2,4,6-Trimethylphenylsulfonate)
tert-AMyl Ethyl Ether,1,1-DiMethylpropyl Ethyl Ether
Acetone O-(2,4,6-Trimethylphenylsulfonyl)oxime
O-(2,4,6-Trimethylphenylsulfonyl)acetoxime | [Molecular Formula]
C11H15NO3S | [MDL Number]
MFCD01321127 | [MOL File]
81549-07-7.mol | [Molecular Weight]
241.31 |
| Chemical Properties | Back Directory | [Melting point ]
96 °C | [Boiling point ]
366.4±52.0 °C(Predicted) | [density ]
1.13±0.1 g/cm3(Predicted) | [solubility ]
almost transparency in Methanol | [form ]
powder to crystal | [color ]
White to Almost white |
| Hazard Information | Back Directory | [Preparation]
Preparative Method: Acetone reacts with Hydroxylamine hydrochloride in methanol-aq. NaOH solution to yield acetoxime, which is also commercially available. Acetoxime reacts with 2,4,6- trimethylbenzenesulfonyl chloride in triethylamine-DMF to yield acetoxime O-(2,4,6- trimethylphenylsulfonyl)sulfonate. | [Solubility in organics]
ACETOXIME O-(2,4,6-TRIMETHYLPHENYLSULFONATE) can soluble in ether, THF; slightly sol benzene; insol hexane. | [Uses]
ACETOXIME O-(2,4,6-TRIMETHYLPHENYLSULFONATE) is an electrophilic aminating reagent for Grignard reagents. |
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