| Identification | Back Directory | [Name]
N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE | [CAS]
82113-66-4 | [Synonyms]
TMS Triflimide
[Bis(trifluoromethanesulfonyl)amino]trimethylsilane
N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE
N-(Trimethylsilyl)bis(trifluoromethanesulfonyl)imide
[Bis(trifluoromethanesulfonyl)amino]trimethylsilane
TMS Triflimide
1,1,1-trifluoro-N-(trifluoroMethylsulfonyl)-N-(triMethylsilyl)MethanesulfonaMide
Methanesulfonamide,1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-N-(trimethylsilyl)- | [Molecular Formula]
C5H9F6NO4S2Si | [MOL File]
82113-66-4.mol | [Molecular Weight]
353.34 |
| Chemical Properties | Back Directory | [Boiling point ]
115 °C / 2mmHg | [density ]
1.543±0.06 g/cm3(Predicted) | [storage temp. ]
Freezer | [solubility ]
soluble in most common organic solvents, commonly
used in dichloromethane, toluene, diethyl ether. | [form ]
clear liquid | [pka]
-26.49±0.70(Predicted) | [color ]
Colorless to Red to Green |
| Hazard Information | Back Directory | [Physical properties]
colorless liquid, bp: 115°C(2 Torr). | [Uses]
Methanesulfonamide, 1,1,1-Trifluoro-
N[(trifluoromethyl)sulfonyl]-
N(trimethylsilyl)-? can be used as Lewis acid catalyst for a variety of organic transformations. | [Preparation]
It is easily prepared in situ through protodesilation
by mixing commercially available allyltrimethylsilane
(or any TMS enol ether) and Tf2NH. Originally prepared
by mixing Tf2NH with trimethylsilane at low temperature or
mixing AgNTf2 with TMSCl. |
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| Company Name: |
Energy Chemical
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| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
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