| Identification | Back Directory | [Name]
PENTAAMMINE(TRIFLUOROMETHANESULFONATO)OSMIUM(III) TRIFLUOROMETHANESULFONATE | [CAS]
83781-30-0 | [Synonyms]
Pentaammine(triflato)osmium(III) triflate
PentaammineOsmium(III)Trifluoromethanesulfonate
pentaammine(trifluoromethanesulfonato)-osmium(iii
pentaammine(trifluoromethanesulfonato)osmium(iii) triflate
PENTAAMMINE(TRIFLUOROMETHANESULFONATO)OSMIUM(III) TRIFLUOROMETHANESULFONATE | [Molecular Formula]
C3H15F9N5O9OsS3 | [MDL Number]
MFCD00216600 | [MOL File]
83781-30-0.mol | [Molecular Weight]
722.59 |
| Chemical Properties | Back Directory | [Melting point ]
~276 °C (lit.) | [form ]
powder | [InChI]
1S/3CHF3O3S.5H3N.Os/c3*2-1(3,4)8(5,6)7;;;;;;/h3*(H,5,6,7);5*1H3;/q;;;;;;;;+3/p-3 | [InChIKey]
HWGAHFXMBKZTPE-UHFFFAOYSA-K | [SMILES]
N.N.N.N.N.[Os+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
36/37/38 | [Safety Statements ]
26-36 | [WGK Germany ]
3 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
Useful for the dearomatization of anilines, and the stereoselective synthesis of cyclohexanediones by osmium(II)-promoted Michael additions to phenols. Precursor to Fischer carbyne complexes. | [reaction suitability]
reagent type: catalyst
core: osmium |
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