| Identification | Back Directory | [Name]
3-Bromo-1-trimethylsilyl-1-propene | [CAS]
84673-88-1 | [Synonyms]
3-Bromo-1-trimethylsilyl-1-propene
Silane, [(1E)-3-bromo-1-propen-1-yl]trimethyl- | [Molecular Formula]
C6H13BrSi | [MDL Number]
MFCD08062395 | [MOL File]
84673-88-1.mol | [Molecular Weight]
193.16 |
| Chemical Properties | Back Directory | [Boiling point ]
88-90 °C/63 mmHg | [storage temp. ]
stable in air, and should be kept in a tightly capped bottle. | [form ]
colorless liquid | [Water Solubility ]
insol H2O; sol most common organic solvents. |
| Hazard Information | Back Directory | [Uses]
3-Bromo-1-trimethylsilyl-1-propene could be used in the preparation of functionalized vinylsilanes.
| [Synthesis]
Bromination (Phosphorus(III) Bromide, 0 °C; N-Bromosuccinimide-Dimethyl Sulfide) of 3-(trimethylsilyl)allyl alcohol, which in turn can be prepared by Sodium Bis(2-methoxyethoxy)aluminum Hydride reduction of 3-trimethylsilylpropargyl alcohol. Allylic bromination of Allyltrimethylsilane gives a mixture of 3-Bromo-1-trimethylsilyl-1-propene and its regioisomers, which is also useful for some applications.
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