| Identification | Back Directory | [Name]
1-Ethyl-3-methylimidazolium diethylphosphate | [CAS]
848641-69-0 | [Synonyms]
EMIM DEP
Enim DEP
EMIM(EtO)2PO2
Basionics? LQ 11
Basionics(R) LQ 11
1-Ethyl-3-methylimidazolium diethylphosphate
1-Ethyl-3-methylimidazolium diethyl phosphate >=98.0% (HPLC) | [EINECS(EC#)]
200-100-5 | [Molecular Formula]
C10H21N2O4P | [MDL Number]
MFCD09953486 | [MOL File]
848641-69-0.mol |
| Chemical Properties | Back Directory | [Melting point ]
19-21°C | [Boiling point ]
196℃ at 101.325kPa | [density ]
1.157 | [vapor pressure ]
1.2-10.9hPa at 25-60℃ | [refractive index ]
n20/D 1.475 | [storage temp. ]
Store below +30°C. | [form ]
Liquid | [color ]
Colorless to Yellow to Orange | [PH]
5-7 (200g/l, H2O, 20℃) | [Water Solubility ]
Fully miscible in water. | [Sensitive ]
Moisture Sensitive | [BRN ]
10726450 | [InChI]
1S/C6H11N2.C4H11O4P/c1-3-8-5-4-7(2)6-8;1-3-7-9(5,6)8-4-2/h4-6H,3H2,1-2H3;3-4H2,1-2H3,(H,5,6)/q+1;/p-1 | [InChIKey]
HQWOEDCLDNFWEV-UHFFFAOYSA-M | [SMILES]
CCn1cc[n+](C)c1.CCOP([O-])(=O)OCC | [LogP]
-0.22 at 25℃ and pH7.5 | [CAS DataBase Reference]
848641-69-0 | [ECW]
5.8 V |
| Hazard Information | Back Directory | [Chemical Properties]
Yellow to orange liquid | [Conductivity]
0.84 mS/cm | [Uses]
It finds its application in improving enzymatic hydrolysis of wheat straw and in the enzymatic in situ saccharification of cellulose in aqueous-ionic liquid media. | [Application]
1-Ethyl-3-methylimidazolium diethylphosphate ([C2mim][(C2)2OPO3]) has high biomass solubilization ability due to hydrogen bond basicity and the potential role of cation to rupture the bacterial cell wall. Specifically， one [(C2)2OPO3] anion can interact with two hydroxyl groups of cellulose, which further supports its ability to dissolve biopolymers having OH functionality. Moreover, the cationic imidazolium part of ([C2mim][(C2)2OPO3]) has been shown to interact with negatively charged phospholipid membrane via strong electrostatic interaction to rupture the bacterial membrane[1]. | [General Description]
1-Ethyl-3-methylimidazolium diethyl phosphate is a low melting, imidazolium-based ionic liquid, which can dissolve cellulose. The solution of cellulose in EMIM DEP-pyridine mixture is stable in time. | [References]
[1] Dubey S, et al. 1-Ethyl-3-methylimidazolium Diethylphosphate Based Extraction of Bioplastic “Polyhydroxyalkanoates” from Bacteria: Green and Sustainable Approach. ACS Sustainable Chemistry & Engineering, 2017; 6: 766–773.
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