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850444-36-9

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850444-36-9 Structure

850444-36-9 Structure
IdentificationBack Directory
[Name]

(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
[CAS]

850444-36-9
[Synonyms]

97% TANIAPHOS
(S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-diMethylaMino)(2-diphenylphosphinophenyl)Methane
(S)-1-Diphenylphosphino-2-[(S)-a-(N,N-dimethylamino)-o-(diphenylphosphinophenyl)-methyl]ferrocene
(S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-diMethylaMino) (2-diphenylphosphinophenyl)Methane TANIAPHOS
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
(S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-
diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
(SP)-1-[(S)-alpha-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene >=97%, optical purity ee: >=99%
Taniaphos SL-T001-2, (2R)-1-[(S)-(Dimethylamino)[2-(diphenylphosphino)phenyl]methyl]-2-(diphenylphosphino)ferrocene (acc to CAS)
[Molecular Formula]

C38H34NP2.C5H5.Fe
[MDL Number]

MFCD08561147
[MOL File]

850444-36-9.mol
[Molecular Weight]

687.581
Chemical PropertiesBack Directory
[alpha ]

-312° ±15° (c 0.5, CHCl3)
[storage temp. ]

2-8°C
[form ]

Powder
[color ]

orange
[Stability:]

store cold
[InChIKey]

DEHRMLQYTSYVBC-ZCLNGFLVSA-N
[SMILES]

[Fe].[CH]1[CH][CH][CH][CH]1.CN(C)[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)c5ccccc5P(c6ccccc6)c7ccccc7
Hazard InformationBack Directory
[Chemical Properties]

Orange powder
[General Description]

sold in collaboration with Solvias AG
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[WGK Germany ]

3
[HS Code ]

29319090
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reactions]

  1. Ligand for the Ru-catalyzed hydrogenation of $-ketoesters, enamides and itaconates.
  2. Ligand for Cu-catalyzed asymmetric conjugate addition of Grignard reagents to cyclic enones.
  3. AgOAc-catalyzed asymmetric amination of glycine Schiff bases with azodicarboxylates. 
Reactions of 850444-36-9
Spectrum DetailBack Directory
[Spectrum Detail]

(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS(850444-36-9)1HNMR
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