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86-60-2

86-60-2 Structure

86-60-2 Structure
IdentificationBack Directory
[Name]

2-NAPHTHYLAMINE-8-SULFONIC ACID
[CAS]

86-60-2
[Synonyms]

BADEN ACID
BADISCHE ACID
AMINOCROCEINIC ACID
2-NAPHTHYLAMINE-8-SULFONIC ACID
7-Naphthylamine-1-sulfonic acid
7-amino-1-naphthalenesulfonicaci
7-aminonaphthalene-1-sulfonicaci
7-aminonaphthalene-1-sulfonic acid
2-Aminonaphthalene-8-Sulfonic Acid
7-AMINO-1-NAPHTHALENESULFONIC ACID
7-azanylnaphthalene-1-sulfonic acid
7-aminonaphthalene-1-sulphonic acid
1-Naphthalenesulfonicacid, 7-amino-
2-NAPHTHYLAMINE-8-SULFONIC ACID ISO 9001:2015 REACH
[EINECS(EC#)]

201-685-0
[Molecular Formula]

C10H9NO3S
[MDL Number]

MFCD00035725
[MOL File]

86-60-2.mol
[Molecular Weight]

223.25
Chemical PropertiesBack Directory
[Appearance]

Colorless needles, partially soluble in water and alkalies, slightly soluble in alcohol.
[Boiling point ]

220°C (rough estimate)
[density ]

1.3588 (rough estimate)
[refractive index ]

1.6500 (estimate)
[pka]

-0.34±0.40(Predicted)
[Water Solubility ]

0.6g/L(20 ºC)
[Uses]

Azo dye intermediate.
Hazard InformationBack Directory
[Chemical Properties]

Colorless needles, partially soluble in water and alkalies, slightly soluble in alcohol.
[Description]

2-Aminonaphthalene-8-sulfonic acid [86- 60-2]. (7-aminonaphthalene-1-sulfonic acid), Badische acid, C10H9NO3S, Mr 223.24, crystallizes from water as needles or prisms although only 0.5 % soluble at 100 ℃. Alkalimetal salts are quite soluble in water. Caustic fusion yields 7-amino-1-naphthol, sulfonation in the cold with 20 % oleum gives 2-aminonaphthalene-6,8-disulfonic acid, but nitration gives a mixture of products. 2-Aminonaphthalene-8-sulfonic acid reacts with diazo compounds to form diazoamino compounds rather than coupling to give azo derivatives.
[Production Methods]

2-Hydroxynaphthalene-8-sulfonic acid is aminated by a Bucherer reaction under conditions similar to those used for Tobias acid.
Safety DataBack Directory
[RIDADR ]

1759
[HazardClass ]

8
[PackingGroup ]

III
Spectrum DetailBack Directory
[Spectrum Detail]

2-NAPHTHYLAMINE-8-SULFONIC ACID(86-60-2)1HNMR
2-NAPHTHYLAMINE-8-SULFONIC ACID(86-60-2)IR1
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