| Identification | Back Directory | [Name]
Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane | [CAS]
861445-91-2 | [Synonyms]
Tris(trimethylsilyl)silyl vinyl ether
2-(Ethenyloxy)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane
Trisilane, 2-(ethenyloxy)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane | [Molecular Formula]
C11H30OSi4 | [MDL Number]
MFCD11656064 | [MOL File]
861445-91-2.mol | [Molecular Weight]
290.7 |
| Chemical Properties | Back Directory | [Melting point ]
51-61 °C | [Fp ]
78 °C | [storage temp. ]
2-8°C | [InChI]
1S/C11H30OSi4/c1-11-12-16(13(2,3)4,14(5,6)7)15(8,9)10/h11H,1H2,2-10H3 | [InChIKey]
WPZQENSANSNYSI-UHFFFAOYSA-N | [SMILES]
C[Si](C)(C)[Si](OC=C)([Si](C)(C)C)[Si](C)(C)C |
| Safety Data | Back Directory | [Hazard Codes ]
F,Xi | [Risk Statements ]
11-36/37/38 | [Safety Statements ]
26-36/37 | [RIDADR ]
UN 1325 4.1/PG 3 | [WGK Germany ]
WGK 3 | [Storage Class]
4.1B - Flammable solid hazardous materials | [Hazard Classifications]
Eye Irrit. 2
Flam. Sol. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
Super Silyl Protecting Groups
Used for:
- Diastereoselective [2+2] cyclizations
- Cross-Aldol cascade reaction
- Diastereoselective sequential reactions for generating polyols
- Accessing distinct diastereomers and 4-component reactions
- Supersilyl-directed aldol reactions
- Strong electron-donating effect of the supersilyl group operates only in the α-position and not in the β-position
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| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
|