| Identification | Back Directory | [Name]
6,7-DIHYDRO-2-PENTAFLUOROPHENYL-5H-PYRROLO(2,1-C)-1,2,4-TRIAZOLIUM TETRAFLUOROBORATE, 97% | [CAS]
862095-91-8 | [Synonyms]
6,7-Dihydro-2-pentafluorophenyl-5H-pyrrolo[2,1-c]-1,2,4-triazoliuM tetrafluoroborat
5H-Pyrrolo[2,1-c]-1,2,4-triazoliuM, 6,7-dihydro-2-(pentafluorophenyl)-, tetrafluoroborate(1-)
6,7-Dihydro-2-pentafluorophenyl-5H-pyrrole[2,1-c]-1,2,4-triazolium tetrafluoroborate, min. 98%
6,7-Dihydro-2-pentafluorophenyl-5H-pyrrolo[2,1-c][1,2,4]triazolium Tetrafluoroborate
2-(2,3,4,5,6-pentafluorophenyl)-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-4-ium,tetrafluoroborate | [Molecular Formula]
C11H7BF9N3 | [MDL Number]
MFCD08459335 | [MOL File]
862095-91-8.mol |
| Chemical Properties | Back Directory | [Melting point ]
245 °C | [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
Powder | [color ]
tan | [InChI]
1S/C11H7F5N3.BF4/c12-6-7(13)9(15)11(10(16)8(6)14)19-4-18-3-1-2-5(18)17-19;2-1(3,4)5/h4H,1-3H2;/q+1;-1 | [InChIKey]
KIWCIWCCQVTPOY-UHFFFAOYSA-N | [SMILES]
F[B-](F)(F)F.Fc1c(F)c(F)c(c(F)c1F)-[n+]2cn3CCCc3n2 |
| Questions And Answer | Back Directory | [Reaction]
- Reagent used in the highly enantioand diastereoselective, catalytic intramolecular Stetter reaction.
- Enantioselective synthesis of β-hydroxy and β-amino esters.
- Organocatalytic iminium ion/carbene reaction cascade for the formation of 2,4-disubstituted cyclopentenones.
- Synthesis of alloand epi-Inositol via the NHC-catalyzed carbocyclization of carbohydrate-derived dialdehydes
|
| Hazard Information | Back Directory | [Uses]
This triazolium catalyst is used for intermolecular homodimerization of aryl aldehydes, intramolecular aldehyde-ketone benzoin cyclizations, and intramolecular Stetter reations. | [reaction suitability]
reagent type: catalyst |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
|