ChemicalBook--->CAS DataBase List--->86318-61-8

86318-61-8

86318-61-8 Structure

86318-61-8 Structure
IdentificationBack Directory
[Name]

TERT-BUTYLDIMETHYLSILYLACETYLENE
[CAS]

86318-61-8
[Synonyms]

ethynyl-t-butyldimethylsilane
(tert-Butyldimethylsilyl)ethyne
(T-BUTYLDIMETHYLSILYL)ACETYLENE
tert-Butyldimethylethynylsilane
TERT-BUTYLDIMETHYLSILYLACETYLENE
ETHYNYL-TERT-BUTYLDIMETHYLSILANE
1-(tert-Butyldimethylsilyl)ethyne
(tert-Butyl)(ethynyl)dimethylsilane
3,3,4,4-Tetramethyl-3-sila-1-pentyne
tert-BUTYLDIMETHYLSILYLACETYLENE 98%
(tert-Butyldimethylsilyl)acetylene,97%
(tert-Butyldimethylsilyl)acetylene
Silane,(1,1-diMethylethyl)ethynyldiMethyl-
(tert-Butyldimethylsilyl)acetyleneEthynyl-tert-butyldimethylsilane
[Molecular Formula]

C8H16Si
[MDL Number]

MFCD00191877
[MOL File]

86318-61-8.mol
[Molecular Weight]

140.3
Chemical PropertiesBack Directory
[Appearance]

Clear colorless liquid
[Melting point ]

98-102℃ (chloroform hexane )
[Boiling point ]

116-117 °C(lit.)
[density ]

0.751 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.451(lit.)
[Fp ]

43 °F
[storage temp. ]

Flammables area
[form ]

powder to lump to clear liquid
[color ]

White or Colorless to Almost white or Almost colorless
[Specific Gravity]

0.751
[Water Solubility ]

Sparingly soluble in water (0.043 g/L at 25°C).
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[BRN ]

1921466
[InChI]

InChI=1S/C8H16Si/c1-7-9(5,6)8(2,3)4/h1H,2-6H3
[InChIKey]

RTYNRTUKJVYEIE-UHFFFAOYSA-N
[SMILES]

[Si](C)(C)(C#C)C(C)(C)C
[CAS DataBase Reference]

86318-61-8
Hazard InformationBack Directory
[Chemical Properties]

Clear colorless liquid
[Uses]

tert-Butyldimethylsilylacetylene may be used in the synthesis of β-alkynylketone and β-alkynyl aldehydes. It participates in Cadiot-Chodkiewicz cross-coupling reaction with various bromoalkynes to afford synthetically useful unsymmetrical diynes.
[General Description]

(tert-Butyldimethylsilyl)acetylene is a bulky trialkylsilyl-protected alkyne. It participates in Cadiot-Chodkiewicz cross-coupling reaction with various bromoalkynes to afford synthetically useful unsymmetrical diynes.
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)
GHS02
[Signal word ]

Danger
[Hazard statements ]

H225
[Precautionary statements ]

P210
[Hazard Codes ]

F
[Risk Statements ]

11
[Safety Statements ]

9-16-23-24/25-29-33
[RIDADR ]

UN 1993 3/PG 2
[WGK Germany ]

3
[F ]

10-21
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29319090
Spectrum DetailBack Directory
[Spectrum Detail]

TERT-BUTYLDIMETHYLSILYLACETYLENE(86318-61-8)IR
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