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866-97-7

866-97-7 Structure

866-97-7 Structure
IdentificationBack Directory
[Name]

TETRAPENTYLAMMONIUM BROMIDE
[CAS]

866-97-7
[Synonyms]

Tetraamylaminium·bromide
TETRAAMYLAMMONIUM BROMIDE
Tetrapentylaminium·bromide
TETRAPENTYLAMMONIUM BROMIDE
TETRA-N-AMYLAMMONIUM BROMIDE
TETRA-N-PENTYLAMMONIUM BROMIDE
TETRAPENTYLAMMONIUM BROMIDE, 99+%
TETRAPENTYLAMMONIUM BROMIDE, FOR IPC
n,n,n-tripentyl-1-pentanaminiubromide
TetrapentylaMMoniuM broMide, 99+% 5GR
TetrapentylaMMoniuM broMide, 99+% 25GR
1-Pentanaminium, N,N,N-tripentyl-, bromide
Tetrapentylammonium bromide ,99% [HPLC grade]
Tetrapentylammoniumbromide=Tetra-n-amylammoniumbr
TetrapentylaMMoniuM broMide, for ion-pair chroMatography
[EINECS(EC#)]

212-756-0
[Molecular Formula]

C20H44BrN
[MDL Number]

MFCD00011856
[MOL File]

866-97-7.mol
[Molecular Weight]

378.47
Chemical PropertiesBack Directory
[Appearance]

WHITE SHINY FLAKES
[Melting point ]

100-101 °C(lit.)
[density ]

0.92333 g/cm3 (35.00℃)
[refractive index ]

1.5260 (estimate)
[storage temp. ]

Inert atmosphere,Room Temperature
[Water Solubility ]

Soluble in water
[form ]

Shiny Flakes
[color ]

White
[PH]

pH(10g/l, 25℃) : 5.0~7.0
[λmax]

λ: 240 nm Amax: 0.04
λ: 250 nm Amax: 0.03
λ: 260 nm Amax: 0.02
λ: 500 nm Amax: 0.02
[BRN ]

3658171
[InChI]

InChI=1S/C20H44N.BrH/c1-5-9-13-17-21(18-14-10-6-2,19-15-11-7-3)20-16-12-8-4;/h5-20H2,1-4H3;1H/q+1;/p-1
[InChIKey]

SPALIFXDWQTXKS-UHFFFAOYSA-M
[SMILES]

[N+](CCCCC)(CCCCC)(CCCCC)CCCCC.[Br-]
[EPA Substance Registry System]

Tetrapentylammonium bromide (866-97-7)
Hazard InformationBack Directory
[Chemical Properties]

WHITE SHINY FLAKES
[Uses]

Tetrapentylammonium bromide can be used:
  • As a versatile structure-directing agent for the synthesis of Zeolite-like heterobimetallic cyanide frameworks.
  • As an alkylating agent for rhodium(I)-catalyzed alkylation reaction of benzylic amines and for N-alkylation of azaheterocycles.
  • As a precursor to prepare a Cobalt-complex, {[(Pentyl)4N]3CoBr3}Cl2, which is used as a catalyst in the synthesis of multiwalled carbon nanotubes (MWCNTs).


Electrochemical synthesis of stable graphite intercalation compounds (GICs) containing tetrapentylammonium cations has been reported.
[General Description]

Tetrapentylammonium bromide is a quaternary ammonium salt with pentyl chains and a bromide counterion, which is generally used as a phase transfer catalyst.
[Purification Methods]

Crystallise it from pet ether, *benzene or acetone/ether mixtures and dry in vacuum at 40-50o for 2 days. It is used in ion-paired chromatography (Sagara et al. J Chromatogr 328 289 1985). [Beilstein 4 IV 677.]
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-37/39
[WGK Germany ]

3
[TSCA ]

TSCA listed
[HS Code ]

29239000
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Sodium hydroxide-->Triethylamine-->acetonitrile-->1-Bromopentane-->Amylamine-->TRIAMYLAMINE-->Tetrapentylammonium iodide
[Preparation Products]

TETRAPENTYLAMMONIUM RHODANIDE
Spectrum DetailBack Directory
[Spectrum Detail]

TETRAPENTYLAMMONIUM BROMIDE(866-97-7)MS
TETRAPENTYLAMMONIUM BROMIDE(866-97-7)1HNMR
TETRAPENTYLAMMONIUM BROMIDE(866-97-7)13CNMR
TETRAPENTYLAMMONIUM BROMIDE(866-97-7)IR1
TETRAPENTYLAMMONIUM BROMIDE(866-97-7)IR2
TETRAPENTYLAMMONIUM BROMIDE(866-97-7)Raman
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