| Identification | Back Directory | [Name]
(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate | [CAS]
866641-66-9 | [Synonyms]
JohnPhos Au(MeCN)SbF6
2-(Di-t-butylphosphino)biphenyl(acetonitrile)gold(I) hexafluoroantiMonate, 99%
(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate
(Acetonitrile)[(biphenyl-2-yl)di-tert-butylphosphine]gold(1+) hexafluoroantimonate
2-(Di-t-butylphosphino))-1,1'-biphenyl(acetonitrile)gold(I) hexafluoroantimonate, 99% | [Molecular Formula]
C22H30AuF6NPSb | [MDL Number]
MFCD11045449 | [MOL File]
866641-66-9.mol |
| Chemical Properties | Back Directory | [Melting point ]
198-203 °C (D) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Powder | [color ]
white to off-white | [Sensitive ]
air sensitive, moisture sensitive | [InChI]
1S/C20H27P.C2H3N.Au.6FH.Sb/c1-19(2,3)21(20(4,5)6)18-15-11-10-14-17(18)16-12-8-7-9-13-16;1-2-3;;;;;;;;/h7-15H,1-6H3;1H3;;6*1H;/q;;+1;;;;;;;+5/p-6 | [InChIKey]
ADQOZROJMVWPRI-UHFFFAOYSA-H | [SMILES]
[Au+].CC#N.F[Sb-](F)(F)(F)(F)F.CC(C)(C)P(c1ccccc1-c2ccccc2)C(C)(C)C |
| Questions And Answer | Back Directory | [Reaction]
- Gold catalyst used in the regio-and stereoselective synthesis of functionalized benzo[b]oxepines.
- Gold catalyst used in the cyclization reactions of o-(buta-1,3-diyn-1-yl-)-substituted N-aryl ureas.
- Gold catalyst used in the cycloisomerization of 1,7-enyne esters to structurally diverse cis-tetrahydropyridin-4-yl ketones.
- Catalyst used in the synthesis of coumarin-containing natural products.
- Catalyst used in the synthesis of benzo[4,5]imidazo[1,2-a]quinazolinones.
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| Company Name: |
Energy Chemical
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| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
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| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
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