| Identification | Back Directory | [Name]
(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate | [CAS]
866641-66-9 | [Synonyms]
JohnPhos Au(MeCN)SbF6 2-(Di-t-butylphosphino)biphenyl(acetonitrile)gold(I) hexafluoroantiMonate, 99% (Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate (Acetonitrile)[(biphenyl-2-yl)di-tert-butylphosphine]gold(1+) hexafluoroantimonate 2-(Di-t-butylphosphino))-1,1'-biphenyl(acetonitrile)gold(I) hexafluoroantimonate, 99% | [Molecular Formula]
C22H30AuF6NPSb | [MDL Number]
MFCD11045449 | [MOL File]
866641-66-9.mol |
| Chemical Properties | Back Directory | [Melting point ]
198-203 °C (D) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Powder | [color ]
white to off-white | [Sensitive ]
air sensitive, moisture sensitive |
| Questions And Answer | Back Directory | [Reaction]
- Gold catalyst used in the regio-and stereoselective synthesis of functionalized benzo[b]oxepines.
- Gold catalyst used in the cyclization reactions of o-(buta-1,3-diyn-1-yl-)-substituted N-aryl ureas.
- Gold catalyst used in the cycloisomerization of 1,7-enyne esters to structurally diverse cis-tetrahydropyridin-4-yl ketones.
- Catalyst used in the synthesis of coumarin-containing natural products.
- Catalyst used in the synthesis of benzo[4,5]imidazo[1,2-a]quinazolinones.

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Sigma-Aldrich
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