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87188-51-0

87188-51-0 Structure

87188-51-0 Structure
IdentificationBack Directory
[Name]

TERT-BUTYL 4-VINYLPHENYL CARBONATE
[CAS]

87188-51-0
[Synonyms]

tbsm
c-1566
4-boc-styrene
p-tert-Butoxycarbonyloxystyrene
4-(tert-Butoxycarbonyloxy)styrene
tert-Butyl p-vinylphenyl carbonate
TERT-BUTYL 4-VINYLPHENYL CARBONATE
p-tert-butoxycarbonyloxystyrenemonomer
TERT-BUTYL 4-VINYLPHENYL CARBONATE 98%
1,1-dimethylethyl4-ethenylphenylcarbonate
carbonicacid,1,1-dimethylethyl4-ethenylphenylester
4-(TERT-BUTOXYCARBONYLOXY)STYRENE;TERT-BUTYL P-VINYLPHENYL CARBONATE
[Molecular Formula]

C13H16O3
[MDL Number]

MFCD00145182
[MOL File]

87188-51-0.mol
[Molecular Weight]

220.26
Chemical PropertiesBack Directory
[Melting point ]

27-29 °C(lit.)
[Boiling point ]

187 °C(lit.)
[density ]

1.1101 (rough estimate)
[refractive index ]

1.5090 (estimate)
[Fp ]

>230 °F
[InChI]

InChI=1S/C13H16O3/c1-5-10-6-8-11(9-7-10)15-12(14)16-13(2,3)4/h5-9H,1H2,2-4H3
[InChIKey]

GJWMYLFHBXEWNZ-UHFFFAOYSA-N
[SMILES]

C(OC1=CC=C(C=C)C=C1)(=O)OC(C)(C)C
[EPA Substance Registry System]

Carbonic acid, 1,1-dimethylethyl 4-ethenylphenyl ester (87188-51-0)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
[WGK Germany ]

2
[RTECS ]

FG0460000
Hazard InformationBack Directory
[Hazard]

Moderately toxic by skin contact. A mild skin irritant.
[Uses]

Used as an intermediate in organic synthesis.
[Application]

Tert-Butyl 4-Vinylphenyl Carbonate (tBVPC) could be used to synthesize a terpolymer, which is a novel chemically amplified positive photoresist with methyl methacrylate (MMA)triphenylsulfonium salt methacrylate (TPSMA). In addition, Lithographic performance of a PAG-bound polymer resist based on tert-butyl 4-vinyl phenyl carbonate, n-[p-(t-butyloxycarbonyloxy) phenyl]maleimide terpolymers as a novel chemically amplified resist exhibited a positive working behavior. They showed 0.18 μm line pattern at electron beam lithography to indicate that the polymer bounded PAG resists have a potential to fabricate nanostructures[1].
[Synthesis]

Tert-Butyl 4-Vinylphenyl Carbonate was prepared by reacting 4-Hydroxystyrene with Di-tert-butyl dicarbonate in prestence of Tetramethylammonium hydroxide in water.
[References]

[1] Jae Beom Yoo . “Triphenylsulfonium salt methacrylate bound polymer resist for electron beam lithography.” Polymer 55 16 (2014): Pages 3599-3604.
Spectrum DetailBack Directory
[Spectrum Detail]

Tert-Butyl 4-Vinylphenyl Carbonate(87188-51-0)1HNMR
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