| Identification | Back Directory | [Name]
(E)-O-(3-Chloro-2-propenyl)hydroxylamine | [CAS]
87851-77-2 | [Synonyms]
intermediate for Clethodim
(3-trans-Chloroallyl)oxyamine
O-(3-Chloroallyl)hydroxylaMine
(E)-O-(3-Chloroallyl)hydroxylamine
O-(3-Chloro-2-propenyl)hydroxylamine
(E)-O-(3-Chloro-2-propenyl)hydroxylamine
Hydroxylamine,O-[(2E)-3-chloro-2-propen-1-yl]- | [Molecular Formula]
C3H6ClNO | [MDL Number]
MFCD09951937 | [MOL File]
87851-77-2.mol | [Molecular Weight]
107.539 |
| Chemical Properties | Back Directory | [Boiling point ]
209 ºC | [density ]
1.155 | [Fp ]
80 ºC | [storage temp. ]
Inert atmosphere,Store in freezer, under -20°C | [solubility ]
Chloroform (Slightly), Ethyl Acetate (Slightly) | [form ]
Oil | [pka]
3.80±0.70(Predicted) | [color ]
Clear Colourless | [InChI]
InChI=1S/C3H6ClNO/c4-2-1-3-6-5/h1-2H,3,5H2/b2-1+ | [InChIKey]
XGNHRRHYGMFKAQ-OWOJBTEDSA-N | [SMILES]
NOC/C=C/Cl |
| Hazard Information | Back Directory | [Uses]
(3-trans-Chloroallyl)oxyamine is used as a reagent in the preparation of 5-(dioxabicyclohept-6-yl)cyclohexenone oxime ether as hericides and plant growth regulators. | [Synthesis]
3-Bromo-2-chloropropene (1.4 mL, 13 mmol, 1.1 eq.) and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU; 1.8 mL, 12 mmol, 1.0 eq.) were sequentially added to dichloromethane. A solution of 2-hydroxyisoindoline-1,3-dione (N-hydroxyphthalimide; 2.0 g, 12 mmol, 1. |
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