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9011-11-4

9011-11-4 Structure

9011-11-4 Structure
IdentificationBack Directory
[Name]

POLY(STYRENE-CO-ALPHA-METHYLSTYRENE)
[CAS]

9011-11-4
[Synonyms]

Kristalex 5140
NORSOLENE W 140
Styrene-α-methylstyrene polymer
poly(styrene-co-α-methylstyrene)
Poly(styrene-co-α-methylstyrene)
Styrol, a-methylstyrol, copolymer
POLY(STYRENE-CO-ALPHA-METHYLSTYRENE)
ethenyl-benzenpolymerwith(1-methylethenyl)benzene
Benzene,ethenyl-,polymerwith(1-methylethenyl)benzene
POLY(STYRENE-CO-ALPHA-METHYLSTYRENE) ISO 9001:2015 REACH
POLY(STYRENE-CO-ALPHA-METHYLSTYRENE), SO FTENING POINT 100 DEG. C
POLY(STYRENE-CO-ALPHA-METHYLSTYRENE), SO FTENING POINT 119 DEG. C
Ethenylbenzene,copolymerwith(1-methylethenyl)benzene,(.alpha.-Methylstyrene-styrene)copolymer
[Molecular Formula]

C17H18
[MDL Number]

MFCD00284291
[MOL File]

9011-11-4.mol
[Molecular Weight]

222.325
Chemical PropertiesBack Directory
[Melting point ]

171-188 °C
[density ]

1.07 g/mL at 25 °C
[solubility ]

hydrocarbons, esters and ketones: soluble
[form ]

solid
[Water Solubility ]

hydrocarbons, esters and ketones: soluble
water, alcohols and glycols: insoluble
[EPA Substance Registry System]

Benzene, ethenyl-, polymer with (1-methylethenyl)benzene (9011-11-4)
Safety DataBack Directory
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

Additive to sealants, caulks, adhesives, and coatings.
[Preparation]

a-Methylstyrene is obtained from benzene and propylene by the following route:

9011-11-4 synthesis


a-Methylstyrene is not readily polymerized by free radical initiators but it is susceptible to cationic polymerization. Polymerization can be effected, for example, in ethyl chloride at -130??C with aluminium chloride but poly(a-methylstyrene) prepared in this manner is a clear brittle solid which has little commercial application. Polymers with much lower molecular weight (300-600) obtained by using alkaline earth catalysts, however, are viscous liquids and have found some use as plasticizers in surface coatings and adhesives.
Styrene-a-methylstyrene copolymers are marketed for extrusion and injection moulding. Compared to polystyrene, these copolymers have the advantage of higher softening points (104-106??C); they too are transparent and colourless.
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