| Identification | Back Directory | [Name]
4-AZIDOANILINE HYDROCHLORIDE | [CAS]
91159-79-4 | [Synonyms]
4-Azidoaniline HCl
4-AZIDOANILINE HYDROCHLORIDE
4-Azidoaniline hydrochloride 97%
4-AMINOPHENYL AZIDE HYDROCHLORIDE | [EINECS(EC#)]
628-425-2 | [Molecular Formula]
C6H7ClN4 | [MDL Number]
MFCD00043274 | [MOL File]
91159-79-4.mol | [Molecular Weight]
170.6 |
| Chemical Properties | Back Directory | [Melting point ]
165 °C (dec.)(lit.) | [solubility ]
methanol: soluble | [BRN ]
7942921 | [InChI]
1S/C6H6N4.ClH/c7-5-1-3-6(4-2-5)9-10-8;/h1-4H,7H2;1H | [InChIKey]
SDYAJRBHPPWHSF-UHFFFAOYSA-N | [SMILES]
Cl.Nc1ccc(cc1)N=[N+]=[N-] |
| Safety Data | Back Directory | [Hazard Codes ]
F,T | [Risk Statements ]
11-23/24/25-36/37/38 | [Safety Statements ]
16-26-33-36/37-45 | [RIDADR ]
UN 2926 4.1/PG 2 | [WGK Germany ]
3 | [F ]
3-8-10 | [HazardClass ]
4.1 | [PackingGroup ]
III | [Storage Class]
4.1B - Flammable solid hazardous materials | [Hazard Classifications]
Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Eye Irrit. 2
Flam. Sol. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
4-Azidoaniline hydrochloride is suitable for use in the preparation of photo-reactive polymers, poly(acrylic acid) having encorporated phenylazido groups. It may be used in the preparation of 1-(4-aminophenyl)-1H-[1,2,3]-triazol-4-ylcarbonyl-Phe-Gly-Phe-Gly-OH. It is suitable for use in the synthesis of photo-reactive polysaccharides. | [reaction suitability]
reaction type: click chemistry | [Purification Methods]
Purify it in EtOAc with dry HCl gas followed by cold dry Et2O. The free base has m 66o(dec) (MeOH) and the picrate has m 64-65o(dec) (MeOH). The IR has max (Nujol) at 2110cm-1 (N3). [Escher et al. Helv Chim Acta 62 1217 1979, Maffei & Rivolta Gazetta Chim Ital 84 750 1954, Beilstein 12 H 772, 12 IV 1741.] |
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| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
|