| Identification | Back Directory | [Name]
(R)-(+)-7,7'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE, MIN. 97% (R)-SDP | [CAS]
917377-74-3 | [Synonyms]
(R)-(+)-7,7′-Bis(diphenylphosphino)-2,2′,3,3′-tetrahydro-1,1′-spirobiindene
(R)-(+)-7,7'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE, MIN. 97% (R)-SDP
1,1'-[(1R)-2,2',3,3'-Tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-diphenylphosphine],99%e.e. | [Molecular Formula]
C41H34P2 | [MDL Number]
MFCD08459344 | [MOL File]
917377-74-3.mol | [Molecular Weight]
588.66 |
| Chemical Properties | Back Directory | [Melting point ]
200-202°C | [alpha ]
+207° (c 0.5, CH2Cl2) | [Boiling point ]
690.2±55.0 °C(Predicted) | [storage temp. ]
?20°C | [form ]
solid | [color ]
white | [Optical Rotation]
[α]22/D +184°, c = 1 in chloroform | [Sensitive ]
air sensitive | [InChIKey]
DKZNVWNOOLQCMJ-UHFFFAOYSA-N | [SMILES]
P(C1=CC=CC2=C1C1(C3=C(CC1)C=CC=C3P(C1=CC=CC=C1)C1=CC=CC=C1)CC2)(C1=CC=CC=C1)C1=CC=CC=C1 |
| Questions And Answer | Back Directory | [Uses]
- Ligands used for the ruthenium-catalyzed hydrogenation of simple and cyclic ketones with high activity and enantioselectivity.
- Ligands used for palladium-catalyzed asymmetric allylic alkylations.
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