| Identification | Back Directory | [Name]
(S)-5-Benzyl-2-Mesityl-6,6-diMethyl-6,8-dihydro-5H-[1,2,4]triazolo[3,4-C][1,4]oxazin-2-iuM tetrafluoroborate | [CAS]
925706-40-7 | [Synonyms]
(5S)-5-benzyl-6,6-dimethyl-2-(2,4,6-trimethylphenyl)-5,8-dihydro-[1,2,4]triazolo[3,4-c][1,4]oxazin-4-ium
(S)-5-Benzyl-2-Mesityl-6,6-diMethyl-6,8-dihydro-5H-[1,2,4]triazolo[3,4-C][1,4]oxazin-2-iuM tetrafluoroborate | [Molecular Formula]
C23H28BF4N3O | [MDL Number]
MFCD16621403 | [MOL File]
925706-40-7.mol | [Molecular Weight]
449.3 |
| Chemical Properties | Back Directory | [Melting point ]
200-206°C | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
solid | [InChI]
1S/C23H28N3O.BF4/c1-16-11-17(2)22(18(3)12-16)26-15-25-20(13-19-9-7-6-8-10-19)23(4,5)27-14-21(25)24-26;2-1(3,4)5/h6-12,15,20H,13-14H2,1-5H3;/q+1;-1/t20-;/m0./s1 | [InChIKey]
PVYSZYZMWZCJCT-BDQAORGHSA-N | [SMILES]
F[B-](F)(F)F.CC1=C(C(C)=CC(C)=C1)[N+]2=CN3C(COC(C)(C)[C@@H]3CC4=CC=CC=C4)=N2 |
| Hazard Information | Back Directory | [Uses]
Catalyst for:
- Intermolecular conjugate addition of alcohols to unsaturated ketones and esters
- Preparation of β-amino carbonyl compounds by N-heterocyclic carbene-catalyzed enantioselective Mannich reactions of a-aryloxyacetaldehydes with imines
- Asymmetric synthesis of cyclopentenes from allyl diketones by carbene-catalyzed intramolecular aldol reaction, lactonization, and carbon dioxide expulsion
- Preparation of esters via tandem oxidation of allylic/benzylic/propargyl alcohols or aldehyde
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Sigma-Aldrich
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021-61415566 800-8193336 |
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https://www.sigmaaldrich.cn |
| Company Name: |
Energy Chemical
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021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
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