| Identification | Back Directory | [Name]
SODIUM THIOPHENOXIDE | [CAS]
930-69-8 | [Synonyms]
Phenylthio
Phenylthiosodium
Sodiothiobenzene
sodiumthiophenate
SodiuM thiophenol
sodiumthiophenylate
sodiumphenylsulfide
(Phenylthio) sodium
sodiumphenylthiolate
SODIUM THIOPHENOLATE
SODIUM THIOPHENOXIDE
sodiumbenzenethiolate
soudiuM thiophenoxide
THIOPHENOL SODIUM SALT
sodiumphenylmercaptide
Sodium benzenethiol salt
BENZENETHIOL, SODIUM SALT
Sodium Thiophenoxide,>97%
SODIUM THIOPHENOXIDE, tech-95
Sodium thiophenol (solid powder)
BENZENETHIOL, SODIUM SALT, TECH., 90%
SodiuM thiophenolate technical grade, 90%
Sodium Benzenethiolate (technical grade, 90%)
Benzenethiol sodium salt, Sodium thiophenoxide, Thiophenol sodium salt
Sodium thiophenolate,Benzenethiol sodium salt, Sodium thiophenoxide, Thiophenol sodium salt | [EINECS(EC#)]
213-224-0 | [Molecular Formula]
C6H5NaS | [MDL Number]
MFCD00066460 | [MOL File]
930-69-8.mol | [Molecular Weight]
132.16 |
| Questions And Answer | Back Directory | [Preparation]
Sodium thiophenolate is prepared by the following steps:A solution of (11) ( 1.0 g, 2.8 mmol), phenylthiol (0.33 g, 3.0 mmol), acetonitrile (5 cm3) and sodium carbonate (0.3 g) was stirred under reflux for 19 h. Water (20 cm3) was added, then the mixture extracted into DCM. The DCM solution was dried (MgS04) and evaporated to dryness. Chromatography on silica gel with DCM - hexane (30 : 70) as the eluent yielded 2,6-dibromo-3,5-difluoro-4-thiophenoxypyridine (0.9 g, 85%), m.p.65.5-66.5 OC (Found: C, 34.45; H, 1.3; N, 3.2. C11H5Bf2F2NS requires C, 34.7; H, 1.3; N, 3.7%); IR spectrum no. 16; mass spectrum no. 19; nmr spectrum no. 16. |
| Hazard Information | Back Directory | [Uses]
Sodium thiophenolate has been used for the synthesis of MCoTI-I and MCoTI-II cyclotides, which are naturally-occurring cyclic cystine-knot microprotein trypsin inhibitors. It may be employed in the following studies:
- As probe for the immunoassay and for the detection of label-free protein by surface-enhanced Raman scattering (SERS).
- Preparation of new cyclometalated 6-phenyl-4-(p-R-phenyl)-2,2′-bipyridyl (C--N--N)Pt(II) thiophenolate complexes.
- Synthesis of 1,3,5,7,9-pentakis(4-methoxyphenylthio)corannulene, 1,3,5,7,9-pentakis(2-naphthylthio)corannulene and 1,3,6,8-tetrakis(4-methoxyphenylthio)corannulene.
- Synthesis of Et4N+ salts of homoleptic arylthiolate Ti(IV) complex, [Ti(SPh)6]2-.
| [General Description]
Sodium thiophenolate can be prepared from the reaction of sodium and thiophenol in diethyl ether. |
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