| Identification | Back Directory | [Name]
Bis(di-tert-butyl)-4-dimethylaminophenylphosphine | [CAS]
932710-63-9 | [Synonyms]
AMPhos
AMGN-Phos
Aphos 95%
95% A-taPhos
Di-tert-butyl(4-diMethylaMinophenyl)phosphine
4-(Di-tert-butylphosphino)-N,N-dimethylaniline
4-(di-tert-butylphosphanyl)-N,N-dimethylaniline
N,N-Dimethyl 4-(di(tert-butyl)phosphino)aniline
[(4-Dimethylaminophenyl)]di(tert-butyl)phosphine
[4-(Dimethylamino)phenyl]bis(tert-butyl)phosphine
Bis(di-tert-butyl)-4-dimethylaminophenylphosphine
(4-(N,N-diMethylaMino)phenyl)di-t-butylphosphine, 98%
(4-(N,N-DiMethylaMino)phenyl)di-tert-butyl phosphine,95%
[4-(N,N-Dimethylamino)phenyl]di-t-butylphosphine, min. 95%
[4-(N,N-DiMethylaMino)phenyl]di-t-butylphosphine, Min. 95% aMphos
(4-(N,N-DiMethylaMino)phenyl)di-tert-butyl phosphine,95% A-taPhos | [Molecular Formula]
C16H28NP | [MDL Number]
MFCD09265102 | [MOL File]
932710-63-9.mol | [Molecular Weight]
265.378 |
| Chemical Properties | Back Directory | [Melting point ]
57-61°C | [Boiling point ]
349.1±25.0 °C(Predicted) | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
soluble in Acetone | [form ]
crystal | [pka]
4.73±0.24(Predicted) | [color ]
white to light-brown | [InChI]
InChI=1S/C16H28NP/c1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8/h9-12H,1-8H3 | [InChIKey]
IQTHEAQKKVAXGV-UHFFFAOYSA-N | [SMILES]
C1(N(C)C)=CC=C(P(C(C)(C)C)C(C)(C)C)C=C1 | [CAS DataBase Reference]
932710-63-9 |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
36/38 | [Safety Statements ]
26 | [WGK Germany ]
3 | [TSCA ]
No | [HS Code ]
2931499090 | [Storage Class]
8B - Non-combustible, corrosive hazardous materials | [Hazard Classifications]
Skin Corr. 1B |
| Questions And Answer | Back Directory | [Use]
Bis(di-tert-butyl)-4-dimethylaminophenylphosphine is an organophosphine compound and can be used as an organophosphine ligand. | [Reaction]
- Ligand used in a highly-active palladium precatalyst for the efficient amination of aryl chloride.
- Ligand used in the palladium-catalyzed annulations under microwave enhanced conditions.
|
| Hazard Information | Back Directory | [Uses]
Amphos can be used as an electrophotographic photoreceptor, process cartridge, and image forming electrode. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reagent type: ligand
reaction type: Cross Couplings | [References]
[1] Patent: CN105237568, 2017, B. Location in patent: Paragraph 0061-0063 |
|
|